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1ST SYNTHESIS OF SULFONYL SUBSTITUTED TRICARBONYL[ETA(6)-ARENE]CHROMIUM(0) COMPLEXES

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Author(s)

C F MARCOS, S PERRIO, A M Z SLAWIN, S E THOMAS, D J WILLIAMS

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Abstract

Sulfonyl substituted tricarbonyl(eta6-arene)chromium(0) complexes may be prepared by thermolysis of sulfonyl substituted arenes with Cr(CO)6/BuOAc and/or selective oxidation of sulfenyl substituted tricarbonyl(eta6-arene)chromium(0) complexes with cumene hydroperoxide in the presence of a Ti(OPri)4/diethyl tartrate/H2O catalyst.

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Details

Original languageEnglish
Pages (from-to)753-754
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number6
Publication statusPublished - 21 Mar 1994

    Research areas

  • DERIVATIVES, OXIDATIONS, ARENES

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