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3D to 2D Routes to Ultrathin and Expanded Zeolitic Materials

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Author(s)

Pavla Chlubna, Wieslaw J. Roth, Heather Frances Greer, Wuzong Zhou, Oleksiy Shvets, Arnost Zukal, Jiri Cejka, Russell Edward Morris

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Abstract

This contribution reports new methodology we have developed for the disassembly of 3-D UTL framework into 2-D lamellae followed by structure modification including pillaring. This may be widely applicable, particularly to other zeolites that have D4R units present, and so should have great impact also on other porous solids. Specifically, controlled hydrolysis of D4R units in the interlayer space provides individual ultrathin layers with UTL structure by a chemically selective method. Further manipulation of the layers gives a completely novel approach (3D to 2D to pillared) offering hitherto unprecedented opportunities for the preparation of modified zeolites with diverse chemical and structural properties.

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Original languageEnglish
Pages (from-to)542-547
Number of pages6
JournalChemistry of Materials
Volume25
Issue number4
Early online date28 Jan 2013
DOIs
Publication statusPublished - 26 Feb 2013

    Research areas

  • ultrathin zeolites, UTL zeolite, IPC-1PI, two-dimensional zeolites, DELAMINATED ZEOLITE, NANOSHEETS, CRYSTALLIZATION, UTL, TRANSFORMATION, ADSORPTION, PRECURSORS, THICKNESS, FRAMEWORK, CATALYSTS

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