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A Highly Active Manganese Catalyst for Enantioselective Ketone and Ester Hydrogenation

Research output: Contribution to journalArticle

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Author(s)

Magnus B. Widegren, Gavin J. Harkness, Alexandra M. Z. Slawin, David B. Cordes, Matthew L. Clarke

School/Research organisations

Abstract

Anew hydrogenation catalyst based onamanganese complex of a chiral P,N,N ligand has been found to be especially active for the hydrogenation of esters down to 0.1 mol% catalyst loading, and gives up to 97% ee in the hydrogenation of pro-chiral deactivated ketones at 30-50 degrees C.

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Original languageEnglish
Pages (from-to)5825-5828
Number of pages4
JournalAngewandte Chemie International Edition
Volume56
Issue number21
DOIs
Publication statusPublished - 15 May 2017

    Research areas

  • enantioselective catalysis, ester hydrogenation, ferrocene, manganese, reduction, ASYMMETRIC ALKENE HYDROGENATION, CHIRAL TRIDENTATE LIGAND, CARBOXYLIC-ACID ESTERS, C-H ACTIVATION, PINCER COMPLEXES, SELECTIVE HYDROGENATION, IRIDIUM CATALYSTS, RUTHENIUM COMPLEX, AROMATIC KETONES, COBALT CATALYST

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