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A hybrid vanadium fluoride with structurally isolated S=1 kagome layers

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Author(s)

Farida H. Aidoudi, Lewis J. Downie, Russell E. Morris, Mark A. de Vries, Philip Lightfoot

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Abstract

A new organically-templated vanadium(III) fluoride, (NH4)(2)( C2H8N)-[ V3F12], has been prepared using an ionothermal approach. This compound has a unique layered structure featuring distorted S = 1 kagome planes separated by the cationic species. The compound exhibits magnetic frustration, with a canted antiferromagnetic ground state. On further cooling in the ground state a pronounced change in magnetisation kinetics is observed.

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Original languageEnglish
Pages (from-to)6304-6307
Number of pages4
JournalDalton Transactions
Volume43
Issue number17
Early online date13 Feb 2014
DOIs
Publication statusPublished - 2014

    Research areas

  • Magnetic-properties, Oxyfluorides, Lattice, Temperature, Compound

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