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A luminescent [Pd4Ru8]24+ supramolecular cage

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Author(s)

Diego Rota Martir, David B. Cordes, Alexandra M. Z. Slawin, Daniel Escudero, Denis Jacquemin, Stuart Warriner, Eli Zysman-Colman

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Abstract

A phosphorescent cage of the form [Pd4Ru8]24+ is reported. The cage was formed using the metalloligand [Ru(dtbubpy)2(qpy)]2+, where qpy = 4,4’:2’,2’’:4’’,4’’’-quaterpyridine and dtbubpy = 4,4’- ditert-butyl-2,2’-bipyridine. The cage has been characterised by NMR, ESI-MS, TEM and X-ray diffraction analyses and its emission properties elucidated by steady-state and time-resolved emission spectroscopy.
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Original languageEnglish
Pages (from-to)6016-6019
Number of pages4
JournalChemical Communications
Volume54
Issue number47
Early online date14 May 2018
DOIs
Publication statusPublished - 14 Jun 2018

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