Skip to content

Research at St Andrews

A novel copper oxalate, Na2Cu(C2O4)2

Research output: Research - peer-reviewArticle

DOI

Open Access permissions

Open

Author(s)

School/Research organisations

Abstract

A novel copper oxalate Na2Cu(C2O4)2 was synthesized through a hydrothermal method and characterized by single-crystal X-ray diffraction. It crystallizes in monoclinic system, P21/n space group with a = 72578(3) Å, b = 5.7711(4) Å, c = 8.6604(8) Å, β = 106.948(9)°. The structure displays a novel stacking pattern of [Cu(C2O4)2]2– units connected through electrostatic attraction by Na+ cations. Structural comparisons are made to related compounds.
Close

Details

Original languageEnglish
Pages (from-to)1345-1349
Number of pages5
JournalZeitschrift für Anorganische und Allgemeine Chemie
Volume642
Issue number23
Early online date28 Oct 2016
DOIs
StatePublished - 5 Dec 2016

    Research areas

  • Copper oxalate, Hydrothermal synthesis, Single crystal structure, Powder X-ray diffraction

Discover related content
Find related publications, people, projects and more using interactive charts.

View graph of relations

Related by author

  1. A reinvestigation of Na2Fe2(C2O4)2H2O: an iron-based positive electrode for secondary batteries

    Yao, W., Sougrati, M-T., Hoang, K., Hui, J., Lightfoot, P. & Armstrong, A. R. 4 Oct 2017 In : Chemistry of Materials. In press

    Research output: Research - peer-reviewArticle

  2. Na2Fe(C2O4)F2: a new iron-based polyoxyanion cathode for Li/Na ion batteries

    Yao, W., Sougrati, M-T., Hoang, K., Hui, J., Lightfoot, P. & Armstrong, A. R. 14 Mar 2017 In : Chemistry of Materials. 29, 5, p. 2167-2172 6 p.

    Research output: Research - peer-reviewArticle

  3. NaFe3(HPO3)2((H,F)PO2OH)6: a potential cathode material and a novel ferrimagnet

    Munao, I., Zvereva, E., Volkova, O., Vasiliev, A., Armstrong, R. & Lightfoot, P. 7 Mar 2016 In : Inorganic Chemistry. 55, 5, p. 2558-2564 7 p.

    Research output: Research - peer-reviewArticle

  4. Superexchange-mediated negative thermal expansion in Nd-doped BiFeO3

    Kavanagh, C. M., Lightfoot, P. & Morrison, F. D. 14 Dec 2017 In : Journal of Materials Chemistry C. In press

    Research output: Research - peer-reviewArticle

  5. KLi3Fe(C2O4)3: a perovskite-like compound with 1:3 ordering at both A and B sites

    Yao, W., Guo, Y. & Lightfoot, P. 20 Sep 2017 In : Dalton Transactions. Accepted Manuscript

    Research output: Research - peer-reviewArticle

Related by journal

  1. Aluminum and indium complexes derived from guanidines, triazenes, and amidines

    Cole, M. L., Davies, A. J., Jones, C., Junk, P. C., McKay, A. I. & Stasch, A. 8 Oct 2015 In : Zeitschrift für Anorganische und Allgemeine Chemie. 641, 12-13, p. 2233 - 2244 12 p.

    Research output: Research - peer-reviewArticle

  2. A Silver(I) Iodide Complex of a Tellurophosphorane

    Nordheider, A., Slawin, A. M. Z., Woollins, J. D. & Chivers, T. Feb 2015 In : Zeitschrift für Anorganische und Allgemeine Chemie. 641, 2, p. 405-407

    Research output: Research - peer-reviewArticle

  3. Ionic Liquid assisted Synthesis of Zeolite-TON

    Tian, Y., McPherson, M. J., Wheatley, P. S. & Morris, R. E. May 2014 In : Zeitschrift für Anorganische und Allgemeine Chemie. 640, 6, p. 1177-1181

    Research output: Research - peer-reviewArticle

  4. Polymorphism in Li2MSiO4 ( M = Fe, Mn): a variable temperature diffraction study

    Armstrong, A. R., Sirisopanaporn, C., Adamson, P., Billaud, J., Dominko, R., Masquelier, C. & Bruce, P. G. May 2014 In : Zeitschrift für Anorganische und Allgemeine Chemie. 640, 6, p. 1043-1049 7 p.

    Research output: Research - peer-reviewArticle

ID: 247264415