Skip to content

Research at St Andrews

A pyrazolate-stabilized sodium hydride complex

Research output: Contribution to journalArticle

DOI

Author(s)

School/Research organisations

Abstract

The reaction of a sterically demanding sodium pyrazolate complex with n-butylsodium and diphenylsilane afforded the first well-defined molecular sodium hydride complex [(pz)6Na7H] 1 (pz = 3,5-di-tert-butylpyrazolate) that could be structurally characterised.
Close

Details

Original languageEnglish
Pages (from-to)5056 - 5058
Number of pages3
JournalChemical Communications
Volume51
Issue number24
Early online date12 Feb 2015
DOIs
Publication statusPublished - 25 Mar 2015

Discover related content
Find related publications, people, projects and more using interactive charts.

View graph of relations

Related by author

  1. Hydrocarbon-soluble, hexaanionic fulleride complexes of magnesium

    Lawrence, S., Ohlin, C. A., Cordes, D. B., Slawin, A. M. Z. & Stasch, A., 9 Oct 2019, In : Chemical Science. Advance Article , 10 p.

    Research output: Contribution to journalArticle

  2. Thermal rearrangement of a 1,2-bis(silylene): synthesis and crystal structure of a silyl-silylene

    Sidirodopous, A., Stasch, A. & Jones, C., 16 Jul 2019, In : Main Group Metal Chemistry. 42, 1, p. 121-124 4 p., mgmc-2019-0013.

    Research output: Contribution to journalArticle

  3. Anion stabilised hypercloso-hexaalane Al6H6

    Bonyhady, S. J., Collis, D., Holzmann, N., Edwards, A. J., Piltz, R. O., Frenking, G., Stasch, A. & Jones, C., 6 Aug 2018, In : Nature Communications. 9, 6 p., 3079.

    Research output: Contribution to journalArticle

  4. Normal and abnormal NHC coordination in cationic hydride iodide complexes of aluminium

    Trose, M., Burnett, S., Bonyhady, S. J., Jones, C., Cordes, D. B., Slawin, A. M. Z. & Stasch, A., 11 Jul 2018, In : Dalton Transactions. In press

    Research output: Contribution to journalArticle

Related by journal

  1. Chemical Communications (Journal)

    Nigel Peter Botting (Editor)
    2005 → …

    Activity: Publication peer-review and editorial work typesEditor of research journal

Related by journal

  1. Buchwald Hartwig diversification of unprotected halotryptophans, halotryptophan containing tripeptides and the natural product barettin in aqueous conditions

    Renault, Y. J. G., Lynch, R., Marelli, E., Sharma, S. V., Pubill Ulldemolins, C., Sharp, J., Cartmell, C., Cárdenas, P. & Goss, R. J. M., 8 Oct 2019, In : Chemical Communications. Advance Article, 4 p.

    Research output: Contribution to journalReview article

  2. Continuous flow knitting of a triptycene hypercrosslinked polymer

    Lau, C. H., Lu, T., Sun, S-P., Chen, X., Carta, M. & Dawson, D. M., 28 Jul 2019, In : Chemical Communications. 55, 59, p. 8571-8574 4 p.

    Research output: Contribution to journalArticle

  3. Cu-NHC azide complex: synthesis and reactivity

    Trose, M., Nahra, F., Cordes, D. B., Slawin, A. M. Z. & Cazin, C., 14 Oct 2019, In : Chemical Communications. 55, 80, p. 12068-12071

    Research output: Contribution to journalArticle

ID: 244309190

Top