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A simple access to transition metal cyclopropenylidene complexes

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Yannick Daniel Bidal, Mathieu Lesieur, Mohand Melaimi, David Bradford Cordes, Alexandra Martha Zoya Slawin, Guy Bertrand , Catherine S.J. Cazin

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Abstract

We report the first example of BAC–Cu complex (BAC = bis(diisopropylamino)cyclopropenylidene) and its use as a carbene-transfer reagent, allowing access to Au–, Pd–, Ir– and Rh–BAC compounds. Catalytic experiments show the high activity of the [CuCl(BAC)] complex in Click chemistry.
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Original languageEnglish
Pages (from-to)4778-4781
JournalChemical Communications
Volume51
Issue number23
Early online date16 Feb 2015
DOIs
Publication statusPublished - 21 Mar 2015

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