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A simple synthetic entryway into palladium cross-coupling catalysis

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Author(s)

Caroline M. Zinser, Fady Nahra, Marcel Brill, Rebecca E. Meadows, David B. Cordes, Alexandra M. Z. Slawin, Steven P. Nolan, Catherine S. J. Cazin

School/Research organisations

Abstract

The simple synthesis of a family of palladates containing an imidazolium counterion is presented. These ''ate'' complexes can be easily converted into well-defined palladium-N-heterocyclic carbene (NHC) complexes. The synthetic protocols leading to the ''ate'' and to the Pd-NHC neutral complexes have been exemplified with various NHC ligands. The palladates prove efficient pre-catalysts enabling Suzuki-Miyaura and Mizoroki-Heck reactions.

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Details

Original languageEnglish
Pages (from-to)7990-7993
Number of pages4
JournalChemical Communications
Volume53
Issue number57
Early online date11 May 2017
DOIs
Publication statusPublished - 21 Jul 2017

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