Skip to content

Research at St Andrews

A single crystal study of CPO-27 and UTSA-74 for nitric oxide storage and release

Research output: Contribution to journalArticle

DOI

Open Access Status

  • Embargoed (until 14/02/20)

Author(s)

Susan E. Henkelis, Simon M. Vornholt, David B. Cordes, Alexandra M. Z. Slawin, Paul S. Wheatley, Russell E. Morris

School/Research organisations

Abstract

Single crystal CPO-27-Mg, -Zn and its structural isomer UTSA-74 have been prepared through use of acid modulators; salicylic acid and benzoic acid, respectively. Salicylic acid directed the synthesis of CPO-27-Mg/Zn whereas benzoic acid the synthesis of UTSA-74. Through “in-house” SCXRD, DMF was seen to bind to the Zn2+ and water to the Mg2+ metal sites in CPO-27-M. Although the synthesis conditions were analogous for UTSA-74, DMF is too large to bind due to the proximity of the binding sites. A dissolution–recrystallisation transformation was examined from UTSA-74 to CPO-27-Zn. The release of nitric oxide was measured for each material.
Close

Details

Original languageEnglish
Pages (from-to)1857-1861
JournalCrystEngComm
Volume21
Issue number12
Early online date14 Feb 2019
DOIs
Publication statusPublished - 28 Mar 2019

Discover related content
Find related publications, people, projects and more using interactive charts.

View graph of relations

Related by author

  1. Crystal structure resolution of two different chlorhexidine salts

    Cattaneo, D., McCormick, L. J., Cordes, D. B., Slawin, A. M. Z. & Morris, R. E., 5 Oct 2016, In : Journal of Molecular Structure. 1121, p. 70-73 4 p.

    Research output: Contribution to journalArticle

  2. Synthesis and crystallographic characterisation of Mg(H2dhtp)(H2O)5·H2O

    Henkelis, S. E., McCormick, L. J., Cordes, D. B., Slawin, A. M. Z. & Morris, R. E., Mar 2016, In : Inorganic Chemistry Communications. 65, p. 21-23 3 p.

    Research output: Contribution to journalArticle

  3. Electronic effects in mixed N-heterocyclic carbene/phosphite indenylidene ruthenium metathesis catalysts

    Bidal, Y. D., Urbina-Blanco, C. A., Poater, A., Cordes, D. B., Slawin, A. M. Z., Cavallo, L. & Cazin, C. S. J., 14 Aug 2019, In : Dalton Transactions. 48, 30, p. 11326-11337 12 p.

    Research output: Contribution to journalArticle

Related by journal

  1. CrystEngComm (Journal)

    Finlay Morrison (Reviewer)
    2010 → …

    Activity: Publication peer-review and editorial work typesPeer review of manuscripts

Related by journal

  1. An expanded MIL-53-type coordination polymer with a reactive pendant ligand

    Kunicki, H., Chamberlain, T., Clarkson, G., Kashtiban, R., Hooper, J. E., Dawson, D. M., Ashbrook, S. E. & Walton, R., 18 Jul 2018, In : CrystEngComm. Advance Article, 4 p.

    Research output: Contribution to journalArticle

  2. New sarcosine-metal halide complexes related to the ferroelectric TSCC

    Clulow, R. & Lightfoot, P., 28 Jul 2018, In : CrystEngComm. 20, 28, p. 4012-4019 8 p.

    Research output: Contribution to journalArticle

  3. Porous zinc and cobalt 2-nitroimidazolate frameworks with six-membered ring windows and a layered cobalt 2-nitroimidazolate polymorph

    Orsi, A., Price, D. J., Kahr, J., Pillai, R. S., Sneddon, S., Cao, S., Benoit, V., Łozińska, M. M., Cordes, D. B., Slawin, A. M. Z., Llewellyn, P. L., Casely, I., Ashbrook, S. E. M., Maurin, G. & Wright, P. A., 14 Mar 2017, In : CrystEngComm. 19, 10, p. 1377-1388 12 p.

    Research output: Contribution to journalArticle

  4. Probing the average distribution of water in organic hydrate crystal structures with radial distribution functions (RDFs)

    Skyner, R. E., Mitchell, J. B. O. & Groom, C., 28 Jan 2017, In : CrystEngComm. 19, 4, p. 641-652 12 p.

    Research output: Contribution to journalArticle

ID: 258304870