Skip to content

Research at St Andrews

Anion control in the ionothermal synthesis of coordination polymers

Research output: Contribution to journalArticle

DOI

Author(s)

Zhuojia Lin, David S. Wragg, John E. Warren, Russell E. Morris

School/Research organisations

Abstract

Two anionic 3D coordination frameworks (EMIm)(2)[Co-3(TMA)(2)(OAc)(2)] 1 and (EMIm)[Co(TMA)] 2, one condensed hydroxide network [Co-5(OH)(2)(OAc)(8)](H2O)(x) 3, and one 2D layer compound (EMIm)[Co-2(TMA)(4)H-7(22bpy)(2)] 4 were prepared from three relevant ionic liquids of 1-ethyl 3-methyl imidazolium bromide (EMIm-Br), EMIm bistriflamide (EMIm-Tf2N), and mixtures of the two. The use of anions in ionic liquids plays a significant role in solvent polarity/hydrophibicity, which in turn controls the structures of materials formed in the ionothermal synthesis. The use of mixed anion ionic liquids opens up many possibilities to further tailor the properties of ionic liquids for ionothermal synthesis applications. The ionic liquid anions are not incorporated into the resultant materials.

Close

Details

Original languageEnglish
Pages (from-to)10334-10335
Number of pages3
JournalJournal of the American Chemical Society
Volume129
DOIs
Publication statusPublished - 29 Aug 2007

    Research areas

  • IONIC LIQUIDS, ALUMINOPHOSPHATE, FRAMEWORKS, SOLVENT

Discover related content
Find related publications, people, projects and more using interactive charts.

View graph of relations

Related by author

  1. Antibacterial efficacy from NO-releasing MOF–polymer films

    Duncan, M. J., Wheatley, P. S., Coghill, E. M., Vornholt, S. M., Warrender, S. J., Megson, I. L. & Morris, R. E., 7 Oct 2020, In : Materials Advances. 1, 7, p. 2509-2519 11 p.

    Research output: Contribution to journalArticle

  2. Advances in organic anode materials for Na-/K-Ion rechargeable batteries

    Desai, A. V., Morris, R. E. & Armstrong, R., 18 Sep 2020, In : CHEMSUSCHEM. 13, 18, p. 4866-4884 20 p.

    Research output: Contribution to journalReview article

  3. Preventing undesirable structure flexibility in pyromellitate metal organic frameworks

    Hayes, O. G., Warrender, S. J., Cordes, D. B., Duncan, M. J., Slawin, A. M. Z. & Morris, R. E., 15 Jul 2020, In : European Journal of Inorganic Chemistry. 2020, 26, p. 2537-2544 8 p.

    Research output: Contribution to journalArticle

  4. Following the unusual breathing behaviour of 17O-enriched mixed-metal (Al,Ga)-MIL-53 using NMR crystallography

    Rice, C. M., Davis, Z. H., McKay, D., Bignami, G. P. M., Chitac, R. G., Dawson, D. M., Morris, R. E. & Ashbrook, S. E., 14 Jul 2020, In : Physical Chemistry Chemical Physics. 22, 26, p. 14514-14526 13 p.

    Research output: Contribution to journalArticle

  5. Mechanomechanically assisted hydrolysis in the ADOR process

    Rainer, D. N., Rice, C. M., Warrender, S. J., Ashbrook, S. E. & Morris, R. E., 15 Jun 2020, In : Chemical Science. Advance Article, 10 p.

    Research output: Contribution to journalArticle

Related by journal

  1. Journal of the American Chemical Society (Journal)

    David Trevor Richens (Editor)

    2005 → …

    Activity: Publication peer-review and editorial work typesEditor of research journal

Related by journal

  1. A deep blue B,N-doped heptacene emitter that shows both thermally activated delayed fluorescence and delayed fluorescence by triplet triplet annihilation

    Madayanad Suresh, S., Duda, E., Hall, D., Yao, Z., Bagnich, S., Slawin, A. M. Z., Bässler, H., Beljonne, D., Buck, M., Olivier, Y., Köhler, A. & Zysman-Colman, E., 5 Mar 2020, In : Journal of the American Chemical Society. Just Accepted

    Research output: Contribution to journalArticle

  2. Difluorocarbene generation from TMSCF3: kinetics and mechanism of NaI-mediated and Si-induced anionic chain reactions

    García-Domínguez, A., West, T. H., Primozic, J. J., Grant, K. M., Johnston, C. P., Cumming, G. G., Leach, A. G. & Lloyd-Jones, G. C., 26 Aug 2020, In : Journal of the American Chemical Society. 142, 34, p. 14649-14663

    Research output: Contribution to journalArticle

  3. Encoding multiple reactivity modes within a single synthetic replicator

    Robertson, C. C., Kosikova, T. & Philp, D., 15 May 2020, In : Journal of the American Chemical Society. Just Accepted

    Research output: Contribution to journalArticle

  4. Facile, room-temperature 17O enrichment of zeolite frameworks revealed by solid-state NMR spectroscopy

    Pugh, S. M., Wright, P. A., Law, D., Thompson, N. & Ashbrook, S. E., 15 Jan 2020, In : Journal of the American Chemical Society. 142, 2, p. 900-906 7 p.

    Research output: Contribution to journalArticle

  5. Hydrogenative depolymerization of nylons

    Kumar, A., von Wolff, N., Rauch, M., Zou, Y-Q., Shmul, G., Ben-David, Y., Leitus, G., Avram, L. & Milstein, D., 19 Aug 2020, In : Journal of the American Chemical Society. 142, 33, p. 14267-14275

    Research output: Contribution to journalArticle

ID: 646329

Top