Skip to content

Research at St Andrews

Anion control in the ionothermal synthesis of coordination polymers

Research output: Contribution to journalArticle

DOI

Author(s)

Zhuojia Lin, David S. Wragg, John E. Warren, Russell E. Morris

School/Research organisations

Abstract

Two anionic 3D coordination frameworks (EMIm)(2)[Co-3(TMA)(2)(OAc)(2)] 1 and (EMIm)[Co(TMA)] 2, one condensed hydroxide network [Co-5(OH)(2)(OAc)(8)](H2O)(x) 3, and one 2D layer compound (EMIm)[Co-2(TMA)(4)H-7(22bpy)(2)] 4 were prepared from three relevant ionic liquids of 1-ethyl 3-methyl imidazolium bromide (EMIm-Br), EMIm bistriflamide (EMIm-Tf2N), and mixtures of the two. The use of anions in ionic liquids plays a significant role in solvent polarity/hydrophibicity, which in turn controls the structures of materials formed in the ionothermal synthesis. The use of mixed anion ionic liquids opens up many possibilities to further tailor the properties of ionic liquids for ionothermal synthesis applications. The ionic liquid anions are not incorporated into the resultant materials.

Close

Details

Original languageEnglish
Pages (from-to)10334-10335
Number of pages3
JournalJournal of the American Chemical Society
Volume129
DOIs
Publication statusPublished - 29 Aug 2007

    Research areas

  • IONIC LIQUIDS, ALUMINOPHOSPHATE, FRAMEWORKS, SOLVENT

Discover related content
Find related publications, people, projects and more using interactive charts.

View graph of relations

Related by author

  1. Vapour-phase-transport rearrangement technique for the synthesis of new zeolites

    Kasneryk, V., Shamzhy, M., Zhou, J., Yue, Q., Mazur, M., Mayoral, A., Luo, Z., Morris, R. E., Čejka, J. & Opanasenko, M., 12 Nov 2019, In : Nature Communications. 10, 8 p., 5129.

    Research output: Contribution to journalArticle

  2. Fast room temperature lability of aluminosilicate zeolites

    Heard, C. J., Grajciar, L., Rice, C. M., Pugh, S. M., Nachtigall, P., Ashbrook, S. E. & Morris, R. E., 16 Oct 2019, In : Nature Communications. 10, 7 p., 4690.

    Research output: Contribution to journalArticle

  3. Synthesis and structural characterisation of the copper MOF: STAM-NMe2

    McHugh, L. N., Olivera Perez, L., Wheatley, P. S., Cordes, D. B., Slawin, A. M. Z. & Morris, R. E., 28 Sep 2019, In : CrystEngComm. 21, 36, p. 5387-5391

    Research output: Contribution to journalArticle

  4. Sodium naphthalene-2,6-dicarboxylate: an anode for sodium batteries

    Cabañero, J. M., Pimenta, V., Cannon, K., Morris, R. & Armstrong, A. R., 12 Sep 2019, In : CHEMSUSCHEM. Early View

    Research output: Contribution to journalArticle

  5. Metal-organic framework-activated carbon composite materials for the removal of ammonia from contaminated airstreams

    McHugh, L. N., Terracina, A., Wheatley, P. S., Buscarino, G., Smith, M. W. & Morris, R. E., 19 Aug 2019, In : Angewandte Chemie International Edition. 58, 34, p. 11747-11751 5 p.

    Research output: Contribution to journalArticle

Related by journal

  1. Journal of the American Chemical Society (Journal)

    David Trevor Richens (Editor)
    2005 → …

    Activity: Publication peer-review and editorial work typesEditor of research journal

Related by journal

  1. A critical cross-catalytic relationship determines the outcome of competition in a replicator network

    Kosikova, T. & Philp, D., 13 Sep 2019, In : Journal of the American Chemical Society. 139, 36, p. 12579-12590 12 p.

    Research output: Contribution to journalArticle

  2. A picture of disorder in hydrous wadsleyite – under the combined microscope of solid-state NMR spectroscopy and ab initio random structure searching

    McKay, D., Moran, R. F., Dawson, D. M., Griffin, J. M., Sturniolo, S., Pickard, C. J., Berry, A. J. & Ashbrook, S. E., 20 Feb 2019, In : Journal of the American Chemical Society. 141, 7, p. 3024–3036 13 p.

    Research output: Contribution to journalArticle

  3. Compositional persistence in a multicyclic network of synthetic replicators

    Huck, J., Kosikova, T. & Philp, D., 4 Sep 2019, In : Journal of the American Chemical Society. 141, 35, p. 13905-13913

    Research output: Contribution to journalArticle

  4. Ensemble-based modeling of the NMR spectra of solid solutions: cation disorder in Y2(Sn,Ti)2O7

    Moran, R. F., McKay, D., Tornstrom, P., Aziz, A., Fernandes, A., Grau-Crespo, R. & Ashbrook, S. E., 6 Nov 2019, In : Journal of the American Chemical Society. 141, 44, p. 17838-17846

    Research output: Contribution to journalArticle

  5. Kinetics and mechanism of the hydrolysis and rearrangement processes within the Assembly-Disassembly-Organization-Reassembly synthesis of zeolites

    Henkelis, S. E., Mazur, M., Rice, C. M., Wheatley, P. S., Ashbrook, S. E. M. & Morris, R. E., 13 Mar 2019, In : Journal of the American Chemical Society. 141, 10, p. 4453-4459 7 p.

    Research output: Contribution to journalArticle

ID: 646329

Top