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Application of palladium (trioxo-adamantyl cage phosphine)chloride complexes as catalysts for the alkoxycarbonylation of styrene; Pd catalysed tert-butoxycarbonylation of styrene

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Author(s)

José Antonio Fuentes García, Alexandra M. Z. Slawin, Matthew L. Clarke

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Abstract

Pre-catalysts of type [PdCl(allyl)(monophosphine)] where the monophosphine is one of the tri-oxo-adamantyl cage phosphines such as 1,3,5,7-tetramethyl-6-phenyl-2,4,8-trioxo-6-phospha-adamantane give very high reactivity in the regioselective hydroxy-carbonylation and alkoxycarbonylation (hydro-esterification) of styrene at 60 degrees C. This high reactivity enables the use of tert-butanol as nucleophile in the alkoxycarbonylation of styrene.

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Original languageEnglish
Pages (from-to)715-718
Number of pages4
JournalCatalysis Science & Technology
Volume2
Issue number4
DOIs
Publication statusPublished - 2012

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