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Chiral Induction in the Ionothermal Synthesis of a 3-D Coordination Polymer

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Abstract

A new chiral coordination polymer, (BMIm)(2)[Ni(TMA-H)(2)(H2O)(2)], was prepared ionothermally from chiral ionic liquid. The use of L-aspartate as one component of the ionic liquid induces chirality in the resulting solid, despite the fact that the anion is not occluded by the material and that the solid itself is built from only nonchiral building blocks. Without the chiral component, an achiral compound is formed under the same synthesis conditions.

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Original languageEnglish
Pages (from-to)4880-4881
Number of pages3
JournalJournal of the American Chemical Society
Volume129
Issue number16
DOIs
Publication statusPublished - 25 Apr 2007

    Research areas

  • METAL-ORGANIC FRAMEWORKS, IONIC LIQUIDS, SURFACE-AREA, HYDROGEN, CATALYSIS, MIXTURES, TEMPLATE, CRYSTALS, SOLVENTS, STORAGE

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