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CO2 activation by manganese pincer complexes through different modes of metal-ligand cooperation (Special issue on Breaking bonds over many timescales: in celebration of Robin Perutz’s 70th birthday)

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Author(s)

Amit Kumar, Prosenjit Daw, Noel A. E. Jalapa, Gregory Leitus, Linda Shimon, Yehoshoa Ben-David, David Milstein

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Abstract

We report here the activation of CO2 using two Mn-PNN pincer complexes that can exhibit different modes of metal–ligand cooperation amido/amino mode that involves [1,2]-activation of CO2 and dearomatization/aromatization mode that involves [1,3]-activation of CO2. We also compare their catalytic activity for CO2 hydrogenation.
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Original languageEnglish
Pages (from-to)14580-14584
JournalDalton Transactions
Volume48
Early online date4 Sep 2019
DOIs
Publication statusPublished - 21 Oct 2019

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