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Coordination polymers of 5-alkoxy isophthalic acids

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Author(s)

Laura J. McCormick, Samuel A. Morris, Alexandra M. Z. Slawin, Simon J. Teat, Russell E. Morris

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Abstract

The topology of coordination polymers containing 5-alkoxy isophthalic acids and first row transition metals was found to be dependent on the combination of solvent system used and length of the alkyl chain. Four different framework types were identified: Phase A, M6(ROip)5(OH)2(H2O)4·xH2O (M = Co and R = Et, Pr, or nBu, or M = Zn and R = Et); Phase B, M2(ROip)2(H2O) (M = Co or Zn and R = Et, Pr, nBu, or iBu, or M = Mn and R = nBu or iBu); Phase C, Zn3(EtOip)2(OH)2; and Phase D, Zn2(EtOip)2(H2O)3. Preliminary screening of the NO storage and release capabilities of the Co-containing materials is also reported.
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Original languageEnglish
Pages (from-to)5771-5780
Number of pages10
JournalCrystal Growth & Design
Volume16
Issue number10
Early online date23 Aug 2016
DOIs
Publication statusPublished - 5 Oct 2016

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