Skip to content

Research at St Andrews

Coordination polymers of ZnII and 5-methoxy isophthalate

Research output: Contribution to journalArticlepeer-review

DOI

Open Access permissions

Open

Author(s)

Laura Jayne McCormick, Samuel Alexander Morris, Simon J. Teat, Matthew Joseph McPherson, Alexandra Martha Zoya Slawin, Russell Edward Morris

School/Research organisations

Abstract

Solvothermal reaction of Zn(OAc)2 and 5-methoxy isophthalic acid (H2MeOip) in aqueous alcohols ROH (R = H, Me, Et, or iPr) affords four different novel coordination polymers. Zn2(HMeOip)(MeOip)(OAc) (1) forms as a 1D 'ribbon of rings' polymer. Zn6(MeOip)4.5(HMeOip)(OH)2(H2O)2·5.5H2O (2) crystallises as a complex 3D framework. Zn(MeOip)(H2O)2 H2O (3) is a 1D coordination polymer that contains almost planar strips of Zn(MeOip). compound 4, Zn5(MeOip)4(OH)2(H2O)4·H2O, obtained from aqueous iPrOH, crystallises as a 2D polymer containing two crystallographically distinct Zn5(OH)2 clusters. Preliminary nitric oxide release experiments have been conducted.

Close

Details

Original languageEnglish
Pages (from-to)17686-17695
JournalDalton Transactions
Volume44
Issue number40
Early online date21 Sep 2015
DOIs
Publication statusPublished - 28 Oct 2015

Discover related content
Find related publications, people, projects and more using interactive charts.

View graph of relations

Related by author

  1. Preventing undesirable structure flexibility in pyromellitate metal organic frameworks

    Hayes, O. G., Warrender, S. J., Cordes, D. B., Duncan, M. J., Slawin, A. M. Z. & Morris, R. E., 15 Jul 2020, In: European Journal of Inorganic Chemistry. 2020, 26, p. 2537-2544 8 p.

    Research output: Contribution to journalArticlepeer-review

  2. Synthetic and crystallographic investigation of the layered coordination framework copper-1,3-bis(4-carboxyphenyl)-5-ethoxybenzene

    McHugh, L. N., Cordes, D. B., Wheatley, P. S., Slawin, A. M. Z. & Morris, R. E., 2 Jan 2020, In: Crystal Growth & Design. 20, 1, p. 39-42 4 p.

    Research output: Contribution to journalArticlepeer-review

  3. Conversion of a microwave synthesized alkali-metal MOF to carbonaceous anode for Li-ion batteries

    Desai, A. V., Pereira Pimenta, V. J., King, C., Cordes, D. B., Slawin, A. M. Z., Morris, R. E. & Armstrong, R., 2020, In: RSC Advances. 10, 23, p. 13732-13736

    Research output: Contribution to journalArticlepeer-review

  4. Synthesis and structural characterisation of the copper MOF: STAM-NMe2

    McHugh, L. N., Olivera Perez, L., Wheatley, P. S., Cordes, D. B., Slawin, A. M. Z. & Morris, R. E., 28 Sep 2019, In: CrystEngComm. 21, 36, p. 5387-5391

    Research output: Contribution to journalArticlepeer-review

  5. A single crystal study of CPO-27 and UTSA-74 for nitric oxide storage and release

    Henkelis, S. E., Vornholt, S. M., Cordes, D. B., Slawin, A. M. Z., Wheatley, P. S. & Morris, R. E., 28 Mar 2019, In: CrystEngComm. 21, 12, p. 1857-1861

    Research output: Contribution to journalArticlepeer-review

Related by journal

  1. Dalton Transactions (Journal)

    Finlay Morrison (Reviewer)

    2011 → …

    Activity: Publication peer-review and editorial work typesPeer review of manuscripts

Related by journal

  1. Dicerium letterbox-shaped tetraphenolates: f-block complexes designed for two-electron chemistry

    Arnold, P. L., Wang, K., Gray, S. J., Moreau, L. M., Booth, C. H., Curcio, M., Wells, J. A. L. & Slawin, A. M. Z., 21 Jan 2020, In: Dalton Transactions. 49, 3, p. 877-884 8 p.

    Research output: Contribution to journalArticlepeer-review

  2. Structural diversity of lead halide chain compounds, APbX3, templated by isomeric molecular cations

    Guo, Y-Y. & Lightfoot, P., 27 Aug 2020, In: Dalton Transactions. 49, 36, p. 12767-12775 9 p.

    Research output: Contribution to journalArticlepeer-review

  3. Structural variations in (001)-oriented layered lead halide perovskites templated by 1,2,4-triazolium

    Guo, Y-Y., Yang, L-J., McNulty, J. A., Slawin, A. M. Z. & Lightfoot, P., 10 Nov 2020, In: Dalton Transactions. In press

    Research output: Contribution to journalArticlepeer-review

  4. Variable dimensionality in 'hollow' hybrid tin iodide perovskites

    McNulty, J. A., Slawin, A. M. Z. & Lightfoot, P., 26 Oct 2020, In: Dalton Transactions. Advance Articles

    Research output: Contribution to journalArticlepeer-review

  5. A hybrid fluoride layered perovskite, (enH2)MnF4

    Li, T., Clulow, R., Bradford, A., Lee, S. L., Slawin, A. M. Z. & Lightfoot, P., 21 Apr 2019, In: Dalton Transactions. 48, 15, p. 4784-4787 4 p.

    Research output: Contribution to journalArticlepeer-review

ID: 219347483

Top