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Copper(I) complexes bearing carbenes beyond classical N-heterocyclic carbenes: synthesis and catalytic activity in “click chemistry”

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Author(s)

Yannick Daniel Bidal, Mathieu Lesieur, Mohand Melaimi, Fady Nahra, David Bradford Cordes, Kasun Sankalpa Athukorala Arachchige, Alexandra Martha Zoya Slawin, Guy Bertrand, Catherine S.J. Cazin

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Abstract

The synthesis and characterization of abnormal N-heterocyclic carbene, cyclic (alkyl)(amino)carbene, and mesoionic carbene copper(I) complexes are reported. These organometallic species are obtained via a versatile and inexpensive synthetic pathway using readily available reactants, namely copper oxide and iminium salts. The catalytic activity of this series of complexes was evaluated in the [3+2] cycloaddition of alkynes with azides (CuAAC). Outstanding catalytic properties were
observed for the abnormal NHC- and triazolylidene-based copper(I) complexes.

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Details

Original languageEnglish
Pages (from-to)3155–3161
JournalAdvanced Synthesis & Catalysis
Volume357
Issue number14-15
DOIs
Publication statusPublished - 12 Oct 2015

    Research areas

  • Copper, Abnormal carbene, Remote carbene, N-heterocyclic carbene, Click chemistry, [3+2] cycloaddition

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