Skip to content

Research at St Andrews

Crystal structure of 2-phenyl-2λ4,3-ditelluratetracyclo[5.5.2.04,13.010,14]tetradeca-1(12),4,6,10,13-pentaen-2-ylium trifluoromethanesulfonate

Research output: Contribution to journalArticlepeer-review

Author(s)

School/Research organisations

Abstract

In the title compound, C18H13Te2 +CF3O3S-, the TeIIatom of the cation and one O atom of the trifluoromethanesulfonate counter-ion form a close-to-linear Te - Te - O system, with a Te - Te - O angle of 172.3 (1)° and a Te - O distance of 2.816 (5) Å, which may suggest the presence of a three-centre-four-electron (3c-4e) bond. Secondary Te⋯O interactions [3.003 (4) and 3.016 (4) Å], involving the second TeIIatom of the binuclear molecule, are also noted, resulting in a supramolecular layer in the bc plane.

Close

Details

Original languageEnglish
Pages (from-to)o1003-o1004
JournalActa Crystallographica Section E: Structure Reports Online
Volume70
Issue number9
DOIs
Publication statusPublished - 1 Jan 2014

    Research areas

  • acenaphthene, crystal structure, tellurium, triflate

Discover related content
Find related publications, people, projects and more using interactive charts.

View graph of relations

Related by author

  1. Bridging (thionylimido)metal complexes

    McGeachie, L. J. R., Buehl, M., Cordes, D. B., Slawin, A. M. Z. & Woollins, J. D., 27 May 2021, (E-pub ahead of print) In: Inorganic Chemistry. Articles ASAP, 5 p.

    Research output: Contribution to journalArticlepeer-review

  2. Synthesis and single crystal structures of N-substituted benzamides and their chemoselective selenation/reduction derivatives

    Hua, G., Carpenter-Warren, C. L., Cordes, D. B., Slawin, A. M. Z. & Woollins, J. D., 19 Apr 2021, In: Molecules. 26, 8, 10 p., 2367.

    Research output: Contribution to journalArticlepeer-review

  3. Organo phosphorus-sulfur-nitrogen heterocycles from thionation of Schiff bases

    Hua, G., Cordes, D. B., Slawin, A. M. Z. & Woollins, J. D., 24 Feb 2021, In: Zeitschrift für Anorganische und Allgemeine Chemie. 647, 4, p. 239-244 7 p.

    Research output: Contribution to journalArticlepeer-review

  4. Thionylimido complexes

    McGeachie, L. J. R., Carpenter-Warren, C. L., Cordes, D. B., Buehl, M., Gray, S. J., Hua, G., Slawin, A. M. Z. & Woollins, J. D., 27 Nov 2020, In: Zeitschrift für Anorganische und Allgemeine Chemie. 646, 22, p. 1795-1798 5 p.

    Research output: Contribution to journalArticlepeer-review

  5. Diradical character of neutral heteroleptic bis(1,2-dithiolene) metal complexes: case study of [Pd(Me2timdt)(mnt)] (Me2timdt = 1,3-dimethyl-2,4,5-trithioxoimidazolidine; mnt2– = 1,2-dicyano-1,2-ethylenedithiolate)

    Aragoni, M. C., Caltagirone, C., Lippolis, V., Podda, E., Slawin, A. M. Z., Woollins, J. D., Pintus, A. & Arca, M., 13 Nov 2020, (E-pub ahead of print) In: Inorganic Chemistry. Articles ASAP

    Research output: Contribution to journalArticlepeer-review

Related by journal

  1. Crystal structures of 2,2′-bipyridin-1-ium 1,1,3,3-tetracyano-2-ethoxyprop-2-en-1-ide and bis(2,2′-bipyridin-1-ium) 1,1,3,3-tetracyano-2-(dicyano-methylene) propane-1,3-diide

    Setifi, Z., Valkonen, A., Fernandes, M. A., Nummelin, S., Boughzala, H., Setifi, F., Glidewell, C. & Harrison, W. T. A., May 2015, In: Acta Crystallographica. Section E, Structure reports online. 71, 5, p. 509-515 7 p.

    Research output: Contribution to journalArticlepeer-review

  2. The crystal structures of three clozapinium salts: different molecular configurations, and supramolecular assembly in one, two and three dimensions

    Kaur, M., Jasinski, J. P., Yathirajan, H. S., Kavitha, C. N., Glidewell, C. & Harrison, W. T. A., Apr 2015, In: Acta Crystallographica. Section E, Structure reports online. 71, 4, p. 406-413 8 p.

    Research output: Contribution to journalArticlepeer-review

  3. Crystal structure of 3-benzoyl-2-[(5-bromo-2-Hydroxy-3-methoxybenzylidene)amino]-4,5,6,7-tetrahydrobenzo[b]thiophene

    Kaur, M., Jasinski, J. P., Yathirajan, H. S., Glidewell, C., Byrappa, K. & Stoeckli-Evans, H., Feb 2015, In: Acta Crystallographica. Section E, Structure reports online. 71, 2, p. 176-179 4 p.

    Research output: Contribution to journalArticlepeer-review

  4. tert-Butyl N-(thiophen-2-yl)carbamate

    Hsu, G. C., Singer, L. M., Cordes, D. B. & Findlater, M., Sep 2013, In: Acta Crystallographica. Section E, Structure reports online. 69, 9, p. o1413 1 p.

    Research output: Contribution to journalArticlepeer-review

ID: 255442483

Top