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Cs7Sm11[TeO3]12Cl16 and Rb7Nd11[TeO3]12Br16, the new tellurite halides of the tetragonal Rb6LiNd11[SeO3]12Cl16 structure type

Research output: Contribution to journalArticle

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Cs7Sm11[TeO3]12Cl16 and Rb7Nd11[TeO3]12Br16, the new tellurite halides of the tetragonal Rb6LiNd11[SeO3]12Cl16 structure type. / Charkin , Dmitri O. ; Black, Cameron; Downie, Lewis James; Sklovsky, Dmitry E. ; Berdonosov, Peter S. ; Olenev , Andrei V. ; Zhou, Wuzong; Lightfoot, Philip; Dolgikh, Valery A. .

In: Journal of Solid State Chemistry, Vol. 232, 12.2015, p. 56-61.

Research output: Contribution to journalArticle

Harvard

Charkin , DO, Black, C, Downie, LJ, Sklovsky, DE, Berdonosov, PS, Olenev , AV, Zhou, W, Lightfoot, P & Dolgikh, VA 2015, 'Cs7Sm11[TeO3]12Cl16 and Rb7Nd11[TeO3]12Br16, the new tellurite halides of the tetragonal Rb6LiNd11[SeO3]12Cl16 structure type', Journal of Solid State Chemistry, vol. 232, pp. 56-61. https://doi.org/10.1016/j.jssc.2015.08.043

APA

Charkin , D. O., Black, C., Downie, L. J., Sklovsky, D. E., Berdonosov, P. S., Olenev , A. V., ... Dolgikh, V. A. (2015). Cs7Sm11[TeO3]12Cl16 and Rb7Nd11[TeO3]12Br16, the new tellurite halides of the tetragonal Rb6LiNd11[SeO3]12Cl16 structure type. Journal of Solid State Chemistry, 232, 56-61. https://doi.org/10.1016/j.jssc.2015.08.043

Vancouver

Charkin DO, Black C, Downie LJ, Sklovsky DE, Berdonosov PS, Olenev AV et al. Cs7Sm11[TeO3]12Cl16 and Rb7Nd11[TeO3]12Br16, the new tellurite halides of the tetragonal Rb6LiNd11[SeO3]12Cl16 structure type. Journal of Solid State Chemistry. 2015 Dec;232:56-61. https://doi.org/10.1016/j.jssc.2015.08.043

Author

Charkin , Dmitri O. ; Black, Cameron ; Downie, Lewis James ; Sklovsky, Dmitry E. ; Berdonosov, Peter S. ; Olenev , Andrei V. ; Zhou, Wuzong ; Lightfoot, Philip ; Dolgikh, Valery A. . / Cs7Sm11[TeO3]12Cl16 and Rb7Nd11[TeO3]12Br16, the new tellurite halides of the tetragonal Rb6LiNd11[SeO3]12Cl16 structure type. In: Journal of Solid State Chemistry. 2015 ; Vol. 232. pp. 56-61.

Bibtex - Download

@article{2d635361c3764fb8a411fe68d79a731a,
title = "Cs7Sm11[TeO3]12Cl16 and Rb7Nd11[TeO3]12Br16, the new tellurite halides of the tetragonal Rb6LiNd11[SeO3]12Cl16 structure type",
abstract = "Two new rare-earth – alkali – tellurium oxide halides were synthesized by a salt flux technique and characterized by single-crystal X-ray diffraction. The structures of the new compounds Cs7Sm11[TeO3]12Cl16 (I) and Rb7Nd11[TeO3]12Br16 (II) (both tetragonal, space group I4/mcm) correspond to the sequence of [MLn11(TeO3)12] and [M6×16] layers and bear very strong similarities to those of known selenite analogs. We discuss the trends in similarities and differences in compositions and structural details between the Se and Te compounds; more members of the family are predicted.",
keywords = "Lanthanides, Tellurium, Structure elucidation, Crystal engineering, Layered compounds",
author = "Charkin, {Dmitri O.} and Cameron Black and Downie, {Lewis James} and Sklovsky, {Dmitry E.} and Berdonosov, {Peter S.} and Olenev, {Andrei V.} and Wuzong Zhou and Philip Lightfoot and Dolgikh, {Valery A.}",
note = "The authors thank the Russian Foundation for Basic Researches for the support of this work under Grants No. 14-03-00604_a and 12-03-92604-KO_a. The X-ray study of compound II was made possible due to M.V. Lomonosov Moscow State University Programm of Development. PL thanks the University of St Andrews and EPSRC for DTA Studentships to CB and LJD.",
year = "2015",
month = "12",
doi = "10.1016/j.jssc.2015.08.043",
language = "English",
volume = "232",
pages = "56--61",
journal = "Journal of Solid State Chemistry",
issn = "0022-4596",
publisher = "Academic Press Inc.",

}

RIS (suitable for import to EndNote) - Download

TY - JOUR

T1 - Cs7Sm11[TeO3]12Cl16 and Rb7Nd11[TeO3]12Br16, the new tellurite halides of the tetragonal Rb6LiNd11[SeO3]12Cl16 structure type

AU - Charkin , Dmitri O.

AU - Black, Cameron

AU - Downie, Lewis James

AU - Sklovsky, Dmitry E.

AU - Berdonosov, Peter S.

AU - Olenev , Andrei V.

AU - Zhou, Wuzong

AU - Lightfoot, Philip

AU - Dolgikh, Valery A.

N1 - The authors thank the Russian Foundation for Basic Researches for the support of this work under Grants No. 14-03-00604_a and 12-03-92604-KO_a. The X-ray study of compound II was made possible due to M.V. Lomonosov Moscow State University Programm of Development. PL thanks the University of St Andrews and EPSRC for DTA Studentships to CB and LJD.

PY - 2015/12

Y1 - 2015/12

N2 - Two new rare-earth – alkali – tellurium oxide halides were synthesized by a salt flux technique and characterized by single-crystal X-ray diffraction. The structures of the new compounds Cs7Sm11[TeO3]12Cl16 (I) and Rb7Nd11[TeO3]12Br16 (II) (both tetragonal, space group I4/mcm) correspond to the sequence of [MLn11(TeO3)12] and [M6×16] layers and bear very strong similarities to those of known selenite analogs. We discuss the trends in similarities and differences in compositions and structural details between the Se and Te compounds; more members of the family are predicted.

AB - Two new rare-earth – alkali – tellurium oxide halides were synthesized by a salt flux technique and characterized by single-crystal X-ray diffraction. The structures of the new compounds Cs7Sm11[TeO3]12Cl16 (I) and Rb7Nd11[TeO3]12Br16 (II) (both tetragonal, space group I4/mcm) correspond to the sequence of [MLn11(TeO3)12] and [M6×16] layers and bear very strong similarities to those of known selenite analogs. We discuss the trends in similarities and differences in compositions and structural details between the Se and Te compounds; more members of the family are predicted.

KW - Lanthanides

KW - Tellurium

KW - Structure elucidation

KW - Crystal engineering

KW - Layered compounds

UR - http://www.sciencedirect.com/science/article/pii/S0022459615301456#appd001

U2 - 10.1016/j.jssc.2015.08.043

DO - 10.1016/j.jssc.2015.08.043

M3 - Article

VL - 232

SP - 56

EP - 61

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

SN - 0022-4596

ER -

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