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(Deep) blue through-space conjugated TADF emitters based on [2.2]paracyclophanes

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Abstract

The first examples of through-space conjugated thermally activated delayed fluorescence (TADF) emitters based on a [2.2]para- cyclophane (PCP) skeleton with stacked (coplanar) donor-acceptor groups have been synthesized. The optoelectronic properties are studied by the relative configuration, cis (pseudo-geminal) and trans (pseudo-para), of the donor and acceptor groups.
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Original languageEnglish
JournalChemical Communications
VolumeIn press
DOIs
Publication statusPublished - 4 Jul 2018

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