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Dendrimer bound tertiary phosphines for alkene hydroformylation

Research output: Other contribution

Author(s)

L Ropartz, Russell Edward Morris, GP Schwarz, DF Foster, David John Cole-Hamilton

School/Research organisations

Abstract

Dendrimer-based phosphines with 8, 24 and 72 PR2 arms (R = Me, Et. hexyl, Cy or Ph) based on polyhedral oligomeric silsesquioxane (POSS) cores have been synthesized and shown to catalyse hydroformylation reactions, in some cases with higher linear:branched product ratio (1:b) than their monomeric analogues. (C) 2000 Elsevier Science S.A. All rights reserved.

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Details

Original languageEnglish
Volume3
Publication statusPublished - Dec 2000

    Research areas

  • dendrimer, phosphine, rhodium, hydroformylation, alcohols, MEMBRANE REACTOR, FUNCTIONALIZED DENDRIMERS, CARBOSILANE DENDRIMERS, CATALYSTS, COMPLEXES, HYDROCARBONYLATION

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ID: 192092

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