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Diphosphane 2,2′-binaphtho[1,8-de][1,3,2]dithiaphosphinine and the easy formation of a stable phosphorus radical cation

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Abstract

A convenient synthesis route to 2,2’-binaphtho[1,8-de][1,3,2]di-thiaphosphinine (3) was found. Its stable radical cation 3•+ was accessed easily through one-electron oxidation with NOBF4.
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Original languageEnglish
Pages (from-to)6348-6351
JournalDalton Transactions
Volume45
Issue number15
Early online date14 Mar 2016
DOIs
Publication statusPublished - 21 Apr 2016

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