Skip to content

Research at St Andrews

Exploring the Coordination of Cyclic Selenoureas to Gold (I)

Research output: Contribution to journalArticlepeer-review

DOI

Author(s)

David James Nelson, Fady Nahra, David B. Cordes, Alexandra Martha Zoya Slawin, Steven Patrick Nolan

School/Research organisations

Abstract

NHC-derived selenoureas, which are useful for the quantification of NHC electronic properties, are deployed as ligands for Au(I). Surprisingly, while some compounds led to the expected [AuCl(SeUr)] species, selenoureas derived from more π-accepting NHCs unexpectedly furnished crystals of the corresponding [Au(SeUr)2][AuCl2] species, in which ligand rearrangement had occurred.
Close

Details

Original languageEnglish
Pages (from-to)3640-3645
Number of pages6
JournalOrganometallics
Volume33
Issue number13
Early online date2 Jul 2014
DOIs
Publication statusPublished - 14 Jul 2014

Discover related content
Find related publications, people, projects and more using interactive charts.

View graph of relations

Related by author

  1. New variants of (110)-oriented layered lead bromide perovskites, templated by formamidinium or pyrazolium

    Guo, Y., Elliott, C., McNulty, J., Cordes, D., Slawin, A. & Lightfoot, P., 20 Jul 2021, (Accepted/In press) In: European Journal of Inorganic Chemistry. In press

    Research output: Contribution to journalArticlepeer-review

  2. A luminescent 1D silver polymer containing [2.2]paracyclophane ligands

    Mackenzie, C. F. R., Delforce, L., Rota Martir, D., Cordes, D. B., Slawin, A. M. Z. & Zysman-Colman, E., 12 Jul 2021, (Accepted/In press) In: Frontiers in Chemistry.

    Research output: Contribution to journalArticlepeer-review

  3. Wide-bite-angle disphosphine ligands in thermally activated delayed fluorescent copper(I) complexes: impact on the performance of electroluminescence applications

    Li, C., Mackenzie, C. F. R., Said, S. A., Pal, A. K., Haghighatbin, M. A., Babaei, A., Sessolo, M., Cordes, D. B., Slawin, A. M. Z., Kamer, P. C. J., Bolink, H., Hogan, C. F. & Zysman-Colman, E., 1 Jul 2021, (E-pub ahead of print) In: Inorganic Chemistry. Articles ASAP, 17 p.

    Research output: Contribution to journalArticlepeer-review

  4. Synthesis of palladium complexes derived from amido linked N-heterocyclic carbenes and their use in Suzuki cross coupling reactions

    Chauhan, R. S., Nagar, S., Chatterjee, S., Goswami, D., Cordes, D. B., Slawin, A. M. Z. & Tawde, T., 7 Jun 2021, (E-pub ahead of print) In: Zeitschrift für Anorganische und Allgemeine Chemie. Early View, 9 p.

    Research output: Contribution to journalArticlepeer-review

  5. Supramolecular packing of alkyl substituted Janus face all-cis 2,3,4,5,6-pentafluorocyclohexyl motifs

    Clark, J., Taylor, A., Geddis, A., Neyyappadath, R. M., Piscelli, B., Yu, C., Cordes, D. B., Slawin, A. M. Z., Cormanich, R., Guldin, S. & O'Hagan, D., 4 Jun 2021, (E-pub ahead of print) In: Chemical Science. Advance Article, 8 p.

    Research output: Contribution to journalArticlepeer-review

Related by journal

  1. Understanding catalyst structure-selectivity relationships in Pd-catalyzed enantioselective methoxycarbonylation of styrene

    Gallarati, S., Dingwall, P., Fuentes García, J. A., Buehl, M. & Clarke, M. L., 14 Dec 2020, (E-pub ahead of print) In: Organometallics. Articles ASAP, 13 p.

    Research output: Contribution to journalArticlepeer-review

  2. Redox noninnocent nature of acridine-based Pincer complexes of 3d metals and C–C bond formation

    Daw, P., Kumar, A., Oren, D., Espinosa-Jalapa, N. A., Srimani, D., Diskin-Posner, Y., Leitus, G., Shimon, L., Carmieli, R., Ben-David, Y. & Milstein, D., 27 Jan 2020, In: Organometallics. 39, 2, p. 279-285

    Research output: Contribution to journalArticlepeer-review

  3. Structure and dynamics of iron pentacarbonyl

    Portius, P., Buehl, M., George, M., Grevels, F-W. & Turner, J., 11 Nov 2019, In: Organometallics. 38, 21, p. 4288-4297 10 p.

    Research output: Contribution to journalArticlepeer-review

  4. Synthesis, Characterization, and Catalytic Properties of Iridium Pincer Complexes Containing NH Linkers

    Leveson-Gower, R. B., Webb, P. B., Cordes, D. B., Slawin, A. M. Z., Smith, D. M., Tooze, R. P. & Liu, J., 8 Jan 2018, In: Organometallics. 37, 1, p. 30-39 10 p.

    Research output: Contribution to journalArticlepeer-review

  5. Expedient syntheses of neutral and cationic Au(I)–NHC complexes

    Veenboer, R. M. P., Gasperini, D., Nahra, F., Cordes, D. B., Slawin, A. M. Z., Cazin, C. S. J. & Nolan, S. P., 25 Sep 2017, In: Organometallics. 36, 18, p. 3645–3653

    Research output: Contribution to journalArticlepeer-review

ID: 141844758

Top