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Fluoride, bifluoride and trifluoromethyl complexes of iridium(I) and rhodium(I)

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Author(s)

Byron Truscott, Fady Nahra, Alexandra Martha Zoya Slawin, David Bradford Cordes, Steven Patrick Nolan

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Abstract

Herein we report robust methods for the preparation and full characterisation of a range of Ir(I) and Rh(I) fluoride and bifluoride complexes using N-heterocyclic carbenes (NHCs) as ancillary ligands. The processes that link the fluoride and the bifluoride species are investigated and reports of the first Ir–bifluoride and Ir(I)–NHC and Rh(I)–NHC trifluoromethyl complexes are revealed.
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Original languageEnglish
Pages (from-to)62-65
Number of pages4
JournalChemical Communications
Volume51
Issue number1
Early online date27 Oct 2014
DOIs
Publication statusPublished - 4 Jan 2015

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