Skip to content

Research at St Andrews

Highly dense and novel proton conducting materials for SOFC electrolyte

Research output: Contribution to journalArticle

Author(s)

Shahzad Hossain, Abdalla M. Abdalla, Juliana H. Zaini, Cristian D. Savaniu, John T. S. Irvine, Abul Kalam Azad

School/Research organisations

Abstract

Highly dense proton conducting materials of BCZYSZn (BaCe0.8-xZrxY0.15Sm0.05O3-δ (x = 0.15, 0.20) with 4 wt.% ZnO as sintering additive), to be used as an intermediate temperature solid oxide fuel cells (IT-SOFCs) electrolyte, have been processed by the conventional solid state reaction method. The crystalline phase, microstructure, electrical properties, cell performance and chemical stability of the materials have been investigated. The ionic conductivity of BCZYSZn 3 (x = 0.20) material has been measured to be ~2.56 × 10-3 S cm−1 and ~8.32 × 10-3 S cm−1 at 600 °C and 850 °C, respectively in wet 5%H2 in Ar atmosphere. Microstructural characterizations of the zinc containing materials (BCZYSZn) show the formation of highly dense morphology with very large grains. The chemical stability test of BCZYSZn in pure CO2 shows that the material is very stable up to 1000 °C. The maximum power density for the BCZYSZn 3 electrolyte cell is found to be 0.42 W/cm2 at 700 °C under the testing atmosphere. The performed characterizations reveal that these are suitable proton-conducting candidate materials for efficient electrochemical devices.
Close

Details

Original languageEnglish
Pages (from-to)27308-27322
JournalInternational Journal of Hydrogen Energy
Volume42
Issue number44
Early online date6 Oct 2017
DOIs
StatePublished - 2 Nov 2017

    Research areas

  • Perovskite, SOFC, Proton conductor, Electrolyte, Impedance spectroscopy, Power density

Discover related content
Find related publications, people, projects and more using interactive charts.

View graph of relations

Related by author

  1. Analytical solution to heat transfer in compressible laminar flow in a flat minichannel

    Bao, C., Jiang, Z., Zhang, X. & Irvine, J. T. S. 28 Aug 2018 In : International Journal of Heat and Mass Transfer. 127, Part C, p. 975-988 14 p.

    Research output: Contribution to journalArticle

  2. Transition metal chlorides NiCl2, KNiCl3, Li6VCl8 and Li2MnCl4 as alternative cathode materials in primary Li thermal batteries

    Giagloglou, K., Payne, J. L., Crouch, C., Gover, R. K. B., Connor, P. A. & Irvine, J. T. S. 14 Nov 2018 In : Journal of The Electrochemical Society. 165, 14, p. A3510-A3516

    Research output: Contribution to journalArticle

  3. Improved electrochemical performance of LiCoPO4 using eco-friendly aqueous binders

    Kim, E. J., Yue, X., Irvine, J. T. S. & Armstrong, A. R. 1 Nov 2018 In : Journal of Power Sources. 403, p. 11-19 9 p.

    Research output: Contribution to journalArticle

  4. Interface formation and Mn segregation of directly assembled La0.8Sr0.2MnO3 cathode on Y2O3-ZrO2 and Gd2O3-CeO2 electrolytes of solid oxide fuel cells

    He, S., Chen, K., Saunders, M., Quadir, Z., Tao, S., Irvine, J. T. S., Cui, C. Q. & Jiang, S. P. 1 Nov 2018 In : Solid State Ionics. 325, p. 176-188 13 p.

    Research output: Contribution to journalArticle

  5. In-situ studies of high temperature thermal batteries: a perspective

    Payne, J. L., Giagloglou, K., Carins, G. M., Crouch, C., Percival, J. D., Smith, R. I., Gover, R. & Irvine, J. T. S. 25 Oct 2018 (Accepted/In press) In : Frontiers in Energy Research.

    Research output: Contribution to journalArticle

Related by journal

  1. Highly dense and chemically stable proton conducting electrolyte sintered at 1200 °C

    Hossain, S., Abdalla, A. M., Radenahmad, N., Zakaria, A. K. M., Zaini, J. H., Rahman, S. M. H., Eriksson, S. G., Irvine, J. T. S. & Azad, A. K. 11 Jan 2018 In : International Journal of Hydrogen Energy. 43, 2, p. 894-907

    Research output: Contribution to journalArticle

  2. Production and stability of low amount fraction of formaldehyde in hydrogen gas standards

    Bacquart, T., Perkins, M., Ferracci, V., Martin, N. A., Resner, K., Ward, M. K. M., Cassidy, N., Hook, J. B., Brewer, P. J., Irvine, J. T. S., Connor, P. A. & Murugan, A. 29 Mar 2018 In : International Journal of Hydrogen Energy. 43, 13, p. 6711-6722

    Research output: Contribution to journalArticle

  3. Electrochemical performance of different carbon fuels on a hybrid direct carbon fuel cell

    Li, S., Pan, W., Wang, S., Meng, X., Jiang, C. & Irvine, J. T. S. 22 Jun 2017 In : International Journal of Hydrogen Energy. 42, 25, p. 16279-16287 9 p.

    Research output: Contribution to journalArticle

  4. Electrochemical properties and durability of in-situ composite cathodes with SmBa0.5Sr0.5Co2O5+δ for metal supported solid oxide fuel cells

    Irvine, J. T. S., Bae, J., Park, J-Y., Choi, W. S. & Kim, J. H. 12 Jan 2017 In : International Journal of Hydrogen Energy. 42, 2, p. 1212-1220 9 p.

    Research output: Contribution to journalArticle

ID: 251291030