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Identification of products from canthaxanthin oxidation

Research output: Research - peer-reviewArticle

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Author(s)

Raphael C. Mordi, John Christopher Walton

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Abstract

Canthaxanthin is a carotenoid that lacks pro-vitamin A activity but is known to have antioxidant activity. The products of its oxidation in oxygen were found to be mainly substituted apo-carotenals and apo-carotenones. The product profile resembles that obtained in the oxidation of β-carotene, except that with canthaxanthin these products are the 4-oxo-β-apo-carotenals and 4-oxo-β-apo-carotenones. Epoxides and diepoxides were clearly identified from β-carotene oxidation but in contrast, with canthaxanthin, apart from 5,6-epoxy-canthaxanthin, which was detected at the early stage of oxidation and minor quantities of 5,6-epoxy-β-ionone and 5,6-epoxy-4-oxo-β-apo-11-carotenal, no other epoxides were detected. The identities of these products lead us to suggest that the mechanism of canthaxanthin oxidation bears significant similarity to that of β-carotene.
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Original languageEnglish
Pages (from-to)836-840
Number of pages5
JournalFood Chemistry
Volume197
Issue numberPart A
Early online date12 Nov 2015
DOIs
StatePublished - 15 Apr 2016

    Research areas

  • Canthaxanthin, β-Carotene, Carotenoids, Oxidation, Antioxidant, Apo-Carotenoids

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