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Increasing the dimensionality of hybrid vanadium oxyfluorides using ionothermal synthesis

Research output: Contribution to journalArticle

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Author(s)

Farida Himeur Himeur, Phoebe Allan, Simon J. Teat, Richard John Goff, Russell Edward Morris, Philip Lightfoot

School/Research organisations

Abstract

A unique organically-templated vanadium(IV) oxyfluoride, [pyH][V2O2F5] has been prepared using an ionothermal approach. This compound has a novel layered structure which may be considered as arising via condensation of previously known 'ladder-like' structural building units. This suggests that ionothermal synthesis may provide a more effective route to extended network structures in these systems than the more widely explored hydrothermal-based media.

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Details

Original languageEnglish
Pages (from-to)6018-6020
Number of pages3
JournalDalton Transactions
Volume39
Issue number26
Early online date8 Mar 2010
DOIs
Publication statusPublished - 14 Jul 2010

    Research areas

  • (VO)(2)P2O7, TEMPLATE

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