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Ionothermal synthesis and characterization of CoAPO-34 molecular sieve

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Mazlina Musa, Daniel M. Dawson, Sharon E. Ashbrook, Russell E. Morris

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Abstract

The cobalt-doped aluminophosphate molecular sieve, CoAPO-34 (with the chabazite-type topology) was prepared under ionothermal conditions using 1-ethyl-3-methylimidazolium bromide (EMIMBr) ionic liquid in presence of 1,6-hexanediamine (HDA). The HDA is not incorporated in CoAPO-34, but is required to mediate the availability of Co2+ during the synthesis. The material was characterized using powder X-ray diffraction (PXRD), thermogravimetric analysis (TGA) and solid-state NMR spectroscopy. Wideline 31P NMR spectroscopy showed broad signals (∼5000–10000 ppm wide), confirming that paramagnetic cobalt ions are successfully incorporated within the framework of the materials.
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Original languageEnglish
Pages (from-to)336-341
Number of pages6
JournalMicroporous and Mesoporous Materials
Volume239
Early online date28 Sep 2016
DOIs
Publication statusPublished - Feb 2017

    Research areas

  • CoAPO-34, Aluminophosphate, Ionothermal synthesis, 1-ethyl-3-methylimidazolium bromide, 1,6-hexanediamine

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