Skip to content

Research at St Andrews

Ionothermal synthesis of inorganic-organic hybrid materials containing perfluorinated aliphatic dicarboxylate ligands

Research output: Contribution to journalArticle

DOI

Author(s)

Zeric Hulvey, David S. Wragg, Zhuojia Lin, Russell E. Morris, Anthony K. Cheetham

School/Research organisations

Abstract

Two new hybrid inorganic-organic frameworks containing perfluorinated dicarboxylate ligands have been synthesized ionothermally from a mixture of 1-ethyl-3- methylimidazolium bromide (emim-Br), and triflimide (emim-Tf2N). The cobalt(II) tetrafluorosuccinate, [emim](2)[Co(H2O)(2)(O2CCF2CF2CO2)(2)] (1), is a two-dimensional coordination polymer containing anionic framework layers separated by emim cations. When hexafluoroglutaric acid is used in similar reactions, [emim](2)[Co-3(O2CCF2CF2CF2CO2)(4)(H2O)(4)] (2) forms. Like 1, this phase contains anionic layers of cobalt and the fluorinated carboxylate separated by emim cations. These new phases represent the first examples of ionothermally synthesized materials using perfluorinated aliphatic carboxylates.

Close

Details

Original languageEnglish
Pages (from-to)1131-1135
Number of pages5
JournalDalton Transactions
Issue number7
DOIs
Publication statusPublished - 2009

Discover related content
Find related publications, people, projects and more using interactive charts.

View graph of relations

Related by author

  1. Fast room temperature lability of aluminosilicate zeolites

    Heard, C. J., Grajciar, L., Rice, C. M., Pugh, S. M., Nachtigall, P., Ashbrook, S. E. & Morris, R. E., 16 Oct 2019, In : Nature Communications. 10, 7 p., 4690.

    Research output: Contribution to journalArticle

  2. Synthesis and structural characterisation of the copper MOF: STAM-NMe2

    McHugh, L. N., Olivera Perez, L., Wheatley, P. S., Cordes, D. B., Slawin, A. M. Z. & Morris, R. E., 28 Sep 2019, In : CrystEngComm. 21, 36, p. 5387-5391

    Research output: Contribution to journalArticle

  3. Sodium naphthalene-2,6-dicarboxylate: an anode for sodium batteries

    Cabañero, J. M., Pimenta, V., Cannon, K., Morris, R. & Armstrong, A. R., 12 Sep 2019, In : CHEMSUSCHEM. Early View

    Research output: Contribution to journalArticle

  4. Metal-organic framework-activated carbon composite materials for the removal of ammonia from contaminated airstreams

    McHugh, L. N., Terracina, A., Wheatley, P. S., Buscarino, G., Smith, M. W. & Morris, R. E., 17 Jul 2019, In : Angewandte Chemie International Edition. Early View

    Research output: Contribution to journalArticle

  5. Magneto-structural correlations of novel kagomé-type metal organic frameworks

    H. Mohideen, M. I., Lei, C., Tuček, J., Malina, O., Brivio, F., Kasneryk, V., Huang, Z., Mazur, M., Zou, X., Nachtigall, P., Čejka, J. & Morris, R. E., 14 Jun 2019, In : Journal of Materials Chemistry. 7, 22, p. 6692-6697 6 p.

    Research output: Contribution to journalArticle

Related by journal

  1. Dalton Transactions (Journal)

    Finlay Morrison (Reviewer)
    2011 → …

    Activity: Publication peer-review and editorial work typesPeer review of manuscripts

Related by journal

  1. A hybrid fluoride layered perovskite, (enH2)MnF4

    Li, T., Clulow, R., Bradford, A., Lee, S. L., Slawin, A. M. Z. & Lightfoot, P., 21 Apr 2019, In : Dalton Transactions. 48, 15, p. 4784-4787 4 p.

    Research output: Contribution to journalArticle

  2. Conjugated, rigidified bibenzimidazole ancillary ligands for enhanced photoluminescence quantum yields of orange/red-emitting iridium(III) complexes

    Henwood, A. F., Antón-García, D., Morin, M., Rota Martir, D., Cordes, D. B., Casey, C., Slawin, A. M. Z., Lebl, T., Buehl, M. & Zysman-Colman, E., 14 Jul 2019, In : Dalton Transactions. 48, 26

    Research output: Contribution to journalArticle

  3. Electronic effects in mixed N-heterocyclic carbene/phosphite indenylidene ruthenium metathesis catalysts

    Bidal, Y. D., Urbina-Blanco, C. A., Poater, A., Cordes, D. B., Slawin, A. M. Z., Cavallo, L. & Cazin, C. S. J., 14 Aug 2019, In : Dalton Transactions. 48, 30, p. 11326-11337 12 p.

    Research output: Contribution to journalArticle

  4. Perovzalates: a family of perovskite-related oxalates

    Clulow, R., Bradford, A. J., Lee, S. L. & Lightfoot, P., 14 Oct 2019, In : Dalton Transactions. 48, 38, p. 14461-14466 6 p.

    Research output: Contribution to journalArticle

  5. Photophysical investigation of near infrared emitting lanthanoid complexes incorporating tris(2-naphthoyl)methane as a new antenna ligand

    Abad Galán, L., Wada, S., Cameron, L., Sobolev, A., Hasegawa, Y., Zysman-Colman, E., Ogden, M. & Massi, M., 21 Mar 2019, In : Dalton Transactions. 48, 11, p. 3768-3776

    Research output: Contribution to journalArticle

ID: 20566051

Top