Skip to content

Research at St Andrews

University > Research portal > Research publications > Low temperature synthesis study of metal-organic framework C...

Low temperature synthesis study of metal-organic framework CPO-27: investigating metal, solvent and base effects down to -78 °C

Research output: Contribution to journal › Article

DOI

Open Access permissions

Open

Links

Author(s)

Simon M. Vornholt, Susan E. Henkelis, Russell E. Morris

School/Research organisations

Abstract

CPO-27-M (M = Co, Mg, Ni, Zn) metal-organic frameworks have been successfully synthesized at temperatures down to -78 °C in a range of solvent systems and their crystallinity and morphology analyzed by powder X-ray diffraction and scanning electron microscopy. CPO-27-Mg and -Zn could be synthesized at lower temperatures using MeOH-NaOH as the solvent with CPO-27-Zn showing the most crystalline material at -78 °C. CPO-27-Zn afforded the most crystalline samples of all studies in MeOH-TEA. However, in MeOH a non-porous monomeric [Zn(H2dhtp)(H2O)2] complex was formed when no base was present. In THF with base (NaOH, TEA) the reaction produced crystalline MOFs in a controlled and stable manner at low temperatures, whilst the reagents were insoluble in THF at low temperature when no base was present. SEM was used to analyze the morphologies of the products.
Close
More...

Details

Original languageEnglish
Pages (from-to)8298-8303
Number of pages6
JournalDalton Transactions
Volume46
Issue number25
Early online date9 Jun 2017
DOIs
Publication statusPublished - 7 Jul 2017

Discover related content
Find related publications, people, projects and more using interactive charts.

View graph of relations

Related by author

  1. Radial artery access site complications during cardiac procedures, clinical implications and potential solutions: the role of nitric oxide

    Coghill, E. M., Johnson, T., Morris, R. E., Megson, I. L. & Leslie, S. J., 26 Jan 2020, In : World Journal of Cardiology. 12, 1, p. 26-34

    Research output: Contribution to journal › Review article

  2. Synthetic and crystallographic investigation of the layered coordination framework copper-1,3-bis(4-carboxyphenyl)-5-ethoxybenzene

    McHugh, L. N., Cordes, D. B., Wheatley, P. S., Slawin, A. M. Z. & Morris, R. E., 2 Jan 2020, In : Crystal Growth & Design. 20, 1, p. 39-42 4 p.

    Research output: Contribution to journal › Article

  3. Vapour-phase-transport rearrangement technique for the synthesis of new zeolites

    Kasneryk, V., Shamzhy, M., Zhou, J., Yue, Q., Mazur, M., Mayoral, A., Luo, Z., Morris, R. E., Čejka, J. & Opanasenko, M., 12 Nov 2019, In : Nature Communications. 10, 8 p., 5129.

    Research output: Contribution to journal › Article

  4. Fast room temperature lability of aluminosilicate zeolites

    Heard, C. J., Grajciar, L., Rice, C. M., Pugh, S. M., Nachtigall, P., Ashbrook, S. E. & Morris, R. E., 16 Oct 2019, In : Nature Communications. 10, 7 p., 4690.

    Research output: Contribution to journal › Article

  5. Synthesis and structural characterisation of the copper MOF: STAM-NMe2

    McHugh, L. N., Olivera Perez, L., Wheatley, P. S., Cordes, D. B., Slawin, A. M. Z. & Morris, R. E., 28 Sep 2019, In : CrystEngComm. 21, 36, p. 5387-5391

    Research output: Contribution to journal › Article

Related by journal

  1. Dalton Transactions (Journal)

    Finlay Morrison (Reviewer)
    2011 → …

    Activity: Publication peer-review and editorial work types › Peer review of manuscripts

Related by journal

  1. Dicerium letterbox-shaped tetraphenolates: f-block complexes designed for two-electron chemistry

    Arnold, P. L., Wang, K., Gray, S. J., Moreau, L. M., Booth, C. H., Curcio, M., Wells, J. A. L. & Slawin, A. M. Z., 21 Jan 2020, In : Dalton Transactions. 49, 3, p. 877-884 8 p.

    Research output: Contribution to journal › Article

  2. A hybrid fluoride layered perovskite, (enH2)MnF4

    Li, T., Clulow, R., Bradford, A., Lee, S. L., Slawin, A. M. Z. & Lightfoot, P., 21 Apr 2019, In : Dalton Transactions. 48, 15, p. 4784-4787 4 p.

    Research output: Contribution to journal › Article

  3. CO2 activation by manganese pincer complexes through different modes of metal-ligand cooperation (Special issue on Breaking bonds over many timescales: in celebration of Robin Perutz’s 70th birthday)

    Kumar, A., Daw, P., Jalapa, N. A. E., Leitus, G., Shimon, L., Ben-David, Y. & Milstein, D., 21 Oct 2019, In : Dalton Transactions. 48, p. 14580-14584

    Research output: Contribution to journal › Article

  4. Conjugated, rigidified bibenzimidazole ancillary ligands for enhanced photoluminescence quantum yields of orange/red-emitting iridium(III) complexes

    Henwood, A. F., Antón-García, D., Morin, M., Rota Martir, D., Cordes, D. B., Casey, C., Slawin, A. M. Z., Lebl, T., Buehl, M. & Zysman-Colman, E., 14 Jul 2019, In : Dalton Transactions. 48, 26

    Research output: Contribution to journal › Article

  5. Electronic effects in mixed N-heterocyclic carbene/phosphite indenylidene ruthenium metathesis catalysts

    Bidal, Y. D., Urbina-Blanco, C. A., Poater, A., Cordes, D. B., Slawin, A. M. Z., Cavallo, L. & Cazin, C. S. J., 14 Aug 2019, In : Dalton Transactions. 48, 30, p. 11326-11337 12 p.

    Research output: Contribution to journal › Article

ID: 250361556

Top