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Low temperature synthesis study of metal-organic framework CPO-27: investigating metal, solvent and base effects down to -78 °C

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Low temperature synthesis study of metal-organic framework CPO-27 : investigating metal, solvent and base effects down to -78 °C. / Vornholt, Simon M.; Henkelis, Susan E.; Morris, Russell E.

In: Dalton Transactions, Vol. 46, No. 25, 07.07.2017, p. 8298-8303.

Research output: Contribution to journal › Article › peer-review

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Vornholt, SM, Henkelis, SE & Morris, RE 2017, 'Low temperature synthesis study of metal-organic framework CPO-27: investigating metal, solvent and base effects down to -78 °C', Dalton Transactions, vol. 46, no. 25, pp. 8298-8303. https://doi.org/10.1039/C7DT01223C

APA

Vornholt, S. M., Henkelis, S. E., & Morris, R. E. (2017). Low temperature synthesis study of metal-organic framework CPO-27: investigating metal, solvent and base effects down to -78 °C. Dalton Transactions, 46(25), 8298-8303. https://doi.org/10.1039/C7DT01223C

Vancouver

Vornholt SM, Henkelis SE, Morris RE. Low temperature synthesis study of metal-organic framework CPO-27: investigating metal, solvent and base effects down to -78 °C. Dalton Transactions. 2017 Jul 7;46(25):8298-8303. https://doi.org/10.1039/C7DT01223C

Author

Vornholt, Simon M. ; Henkelis, Susan E. ; Morris, Russell E. / Low temperature synthesis study of metal-organic framework CPO-27 : investigating metal, solvent and base effects down to -78 °C. In: Dalton Transactions. 2017 ; Vol. 46, No. 25. pp. 8298-8303.

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@article{9966a6579573470d99ec168bff7a427e,
title = "Low temperature synthesis study of metal-organic framework CPO-27: investigating metal, solvent and base effects down to -78 °C",
abstract = "CPO-27-M (M = Co, Mg, Ni, Zn) metal-organic frameworks have been successfully synthesized at temperatures down to -78 °C in a range of solvent systems and their crystallinity and morphology analyzed by powder X-ray diffraction and scanning electron microscopy. CPO-27-Mg and -Zn could be synthesized at lower temperatures using MeOH-NaOH as the solvent with CPO-27-Zn showing the most crystalline material at -78 °C. CPO-27-Zn afforded the most crystalline samples of all studies in MeOH-TEA. However, in MeOH a non-porous monomeric [Zn(H2dhtp)(H2O)2] complex was formed when no base was present. In THF with base (NaOH, TEA) the reaction produced crystalline MOFs in a controlled and stable manner at low temperatures, whilst the reagents were insoluble in THF at low temperature when no base was present. SEM was used to analyze the morphologies of the products.",
author = "Vornholt, {Simon M.} and Henkelis, {Susan E.} and Morris, {Russell E.}",
note = "We thank the EPSRC (EP/K005499/1) (EP/K503162/1) for their financial support of this project and the EPSRC Capital for Great Technologies (EP/L017008/1).",
year = "2017",
month = jul,
day = "7",
doi = "10.1039/C7DT01223C",
language = "English",
volume = "46",
pages = "8298--8303",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "ROYAL SOC CHEMISTRY",
number = "25",

}

RIS (suitable for import to EndNote) - Download

TY - JOUR

T1 - Low temperature synthesis study of metal-organic framework CPO-27

T2 - investigating metal, solvent and base effects down to -78 °C

AU - Vornholt, Simon M.

AU - Henkelis, Susan E.

AU - Morris, Russell E.

N1 - We thank the EPSRC (EP/K005499/1) (EP/K503162/1) for their financial support of this project and the EPSRC Capital for Great Technologies (EP/L017008/1).

PY - 2017/7/7

Y1 - 2017/7/7

N2 - CPO-27-M (M = Co, Mg, Ni, Zn) metal-organic frameworks have been successfully synthesized at temperatures down to -78 °C in a range of solvent systems and their crystallinity and morphology analyzed by powder X-ray diffraction and scanning electron microscopy. CPO-27-Mg and -Zn could be synthesized at lower temperatures using MeOH-NaOH as the solvent with CPO-27-Zn showing the most crystalline material at -78 °C. CPO-27-Zn afforded the most crystalline samples of all studies in MeOH-TEA. However, in MeOH a non-porous monomeric [Zn(H2dhtp)(H2O)2] complex was formed when no base was present. In THF with base (NaOH, TEA) the reaction produced crystalline MOFs in a controlled and stable manner at low temperatures, whilst the reagents were insoluble in THF at low temperature when no base was present. SEM was used to analyze the morphologies of the products.

AB - CPO-27-M (M = Co, Mg, Ni, Zn) metal-organic frameworks have been successfully synthesized at temperatures down to -78 °C in a range of solvent systems and their crystallinity and morphology analyzed by powder X-ray diffraction and scanning electron microscopy. CPO-27-Mg and -Zn could be synthesized at lower temperatures using MeOH-NaOH as the solvent with CPO-27-Zn showing the most crystalline material at -78 °C. CPO-27-Zn afforded the most crystalline samples of all studies in MeOH-TEA. However, in MeOH a non-porous monomeric [Zn(H2dhtp)(H2O)2] complex was formed when no base was present. In THF with base (NaOH, TEA) the reaction produced crystalline MOFs in a controlled and stable manner at low temperatures, whilst the reagents were insoluble in THF at low temperature when no base was present. SEM was used to analyze the morphologies of the products.

U2 - 10.1039/C7DT01223C

DO - 10.1039/C7DT01223C

M3 - Article

VL - 46

SP - 8298

EP - 8303

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 25

ER -

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