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Macro-mesoporous resorcinol-formaldehyde polymer resins as amorphous metal-free visible light photocatalysts

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Author(s)

Guan Zhang, Chengsheng Ni, Lingjuan Liu, Guixia Zhao, Federica Fina, John Thomas Sirr Irvine

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Abstract

We have demonstrated that resorcinol–formaldehyde resin polymers are good visible light responsive photocatalysts, with band gap energies ranging from ca. 1.80 to 2.00 eV. They were found to be photoactive in terms of decomposition of organic substrates under visible light irradiation. The photocatalytic performance of resins could be markedly enhanced by coupling with electron conducting materials such as reduced graphene oxide. Photocatalytic water oxidation was also achievable on the hybrid reduced graphene oxide/resin catalyst with a sacrificial agent. These industrial widely-used resins exhibit many merits as photocatalysts such as low-cost, high surface area, large pore size and volume, facile preparation and scalability for development of eco-friendly commercial products with “self-cleaning” properties, based on their capability for the oxidative removal of organic pollutants under visible light.
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Original languageEnglish
Pages (from-to)15413-15419
JournalJournal of Materials Chemistry A
Volume3
Issue number30
Early online date3 Jul 2015
DOIs
Publication statusPublished - 14 Aug 2015

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