Skip to content

Research at St Andrews

MAIN GROUP METAL 1,3-DITHIOLE-2-THIONE-4,5-DITHIOLATO (DMIT) COMPOUNDS .3. SYNTHESIS OF TETRABUTYLAMMONIUM BIS(1,3-DITHIOLE-2-THIONE-4,5-DITHIOLATO)DIHALOSTANNATES - CRYSTAL-STRUCTURE OF [BU4N]2[I2SN(DMIT)2]

Research output: Contribution to journalArticlepeer-review

Author(s)

SMSV DOIDGEHARRISON, RA HOWIE, John Thomas Sirr Irvine, JL WARDELL

School/Research organisations

Abstract

Compounds [Bu4N]2[X2Sn(DMIT)2] [X = Br (4) or 1 (5); H2-DMIT = 4,5-dimercapto-1,3-dithiole-2-thione] have been prepared from [Bu4N]2[Zn(DMIT)2] and SnX4 in the presence of Bu4NBr. A crystal structure determination of 5 revealed it to consist of discrete [Bu4N] cations and [I2Sn(DMIT)2] dianions; the geometry about tin in the dianion is octahedral with chelating DMIT ligands and cis-iodide ligands [Sn-I = 2.724(5) and 2.727(3) angstrom; mean Sn-S (trans to I) = 2.560 angstrom and mean Sn-S (trans to S) = 2.530 angstrom]. The chelate bite angles are 82.9(4) and 83.1(4)-degrees.

Close

Details

Original languageEnglish
Pages (from-to)2223-2229
Number of pages7
JournalPolyhedron
Volume11
Issue number17
Publication statusPublished - Sep 1992

    Research areas

  • SUPERCONDUCTOR, TRANSITION, MOLECULAR-STRUCTURE, LIGANDS, CHEMISTRY, X-RAY, COMPLEXES

Discover related content
Find related publications, people, projects and more using interactive charts.

View graph of relations

Related by author

  1. Microwave irradiation synthesis to obtain La0.7-xPrxCa0.3MnO3 perovskites: electrical and electrochemical performance

    Ferrel-Alvarez, A. C., Domínguez-Crespo, M. A., Cong, H., Torres-Huerta, A. M., Palma-Ramírez, D. & Irvine, J. T. S., 15 Jan 2021, In: Journal of Alloys and Compounds. 851, 156882.

    Research output: Contribution to journalArticlepeer-review

  2. Graphitic-C3N4 coated floating glass beads for photocatalytic destruction of synthetic and natural organic compounds in water under UV light

    Hui, J., Pestana, C. J., Caux, M., Gunaratne, H. Q. N., Edwards, C., Robertson, P. K. J., Lawton, L. A. & Irvine, J. T. S., 15 Jan 2021, In: Journal of Photochemistry and Photobiology A: Chemistry. 405, 112935.

    Research output: Contribution to journalArticlepeer-review

  3. Activation of anion redox in P3 structure cobalt-doped sodium manganese oxide via introduction of transition metal vacancies

    Kim, E. J., Mofredj, K., Pickup, D., Chadwick, A., Irvine, J. T. S. & Armstrong, R., 1 Jan 2021, In: Journal of Power Sources. 481, 229010.

    Research output: Contribution to journalArticlepeer-review

  4. Photocatalytic removal of the cyanobacterium Microcystis aeruginosa PCC7813 and four microcystins by TiO2 coated porous glass beads with UV-LED irradiation

    Pestana, C. J., Portela Noronha, J., Hui, J., Edwards, C., Gunaratne, H. Q. N., Irvine, J. T. S., Robertson, P. K. J., Capelo-Neto, J. & Lawton, L. A., 25 Nov 2020, In: Science of the Total Environment. 745, 141154.

    Research output: Contribution to journalArticlepeer-review

  5. Perovskite oxynitride solid solutions of LaTaON2-CaTaO2N with greatly enhanced photogenerated charge separation for solar-driven overall water splitting

    Wang, Y., Kang, Y., Zhu, H., Liu, G., Irvine, J. T. S. & Xu, X., 25 Nov 2020, In: Advanced Science . Early View, 8 p., 2003343.

    Research output: Contribution to journalArticlepeer-review

Related by journal

  1. Synthesis and characterization of a hydrogen bonded metal-organic cocrystal: exploration of its DNA binding study

    Khan, S., Alothman, Z. A., Mohammad, M., Islam, M. S., Slawin, A., Wabaidur, S. M., Islam, M. M. & Mir, M. H., 18 Feb 2020, In: Polyhedron. 114454.

    Research output: Contribution to journalArticlepeer-review

  2. Synthesis, characterization, and structural properties of mercury(II), cadmium(II) and zinc(II) tripiperidinophosphine chalcogenide complexes

    Ebnou, F., M’Haiham, M., Ebeid, K., Carpenter-Warren, C. L., Slawin, A. M. Z., Woollins, J. D., Ben Dhia, M. T. & Sanhoury, M. A., 1 Feb 2019, In: Polyhedron. 159, p. 206-211

    Research output: Contribution to journalArticlepeer-review

  3. A panchromatic, near infrared Ir(III) emitter bearing a tripodal C^N^C ligand as a dye for dye-sensitized solar cells

    Hierlinger, C., Flint, H. V., Cordes, D. B., Slawin, A. M. Z., Gibson, E. A., Jacquemin, D., Guerchais, V. & Zysman-Colman, E., 8 Feb 2018, In: Polyhedron. 140, p. 109-115

    Research output: Contribution to journalArticlepeer-review

  4. Synthesis, structure and magnetic properties of an unusual oligonuclear iron(III)-cobalt(III) compound with oxido-, sulfato- and cyanido-bridging ligands

    Setifi, F., Setifi, Z., Konieczny, P., Glidewell, C., Benmansour, S., Gómez-García, C. J., Grandjean, F., Long, G. J., Pelka, R. & Reedijk, J., 14 Oct 2018, In: Polyhedron. In press

    Research output: Contribution to journalArticlepeer-review

  5. Optimised synthesis and characterisation of 1-adamantyltrimethylphosphonium iodide

    Mansour, R., Nejman, P., Taylor, L. J., Chalmers, B. A., Rey, F., Bengueddach, A., Woollins, J. D., Slawin, A. M. Z. & Kilian, P., 5 Sep 2017, In: Polyhedron. 133, p. 302-306 5 p.

    Research output: Contribution to journalArticlepeer-review

ID: 47285722

Top