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Manufacturing and electrochemical evaluation of sofcroll with the La0.43Ca0.37Ni0.06Ti0.94O3-γ - Zr0.92Y0.08O2-γ anode

Research output: Chapter in Book/Report/Conference proceedingConference contribution

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Author(s)

K. Nowicki, H. Zeng, J. T.S. Irvine

School/Research organisations

Abstract

SOFCRoll is a self-supporting, double spiral design combining the advantages of the planar system, thick film manufacturing techniques and robustness of the tubular design. SOFCRoll cells are produced entirely by tape casting and co-sintering, with a volume of less than 2.5cm3 and a large active surface area that exceeding 20cm2. We are currently investigating the incorporation of the A-site deficient, nickel doped perovskite La0.43Ca0.37Ni0.06Ti0.94O3-γ into the SOFCRoll. In the SOFCRoll with La0.43Ca0.37Ni0.06Ti0.94O3-γ - Zr0.92Y0.08O2-γ fuel electrode, the Zr0.92Y0.08O2-γ electrolyte and (La0.8Sr0.2)0.95MnO3 - Zr0.92Y0.08O2-γ oxygen electrode, the electrochemical poling at 2.3V for a few minutes triggered exsolution of nickel nanoparticles and increased the power density. This paper will present the complete methodology behind SOFCRoll manufacture and ceramic processing, with the results of microstructure analysis, shrinking of individual components and recent performance tests.

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Details

Original languageEnglish
Title of host publicationSolid Oxide Fuel Cells 16, SOFC XVI
EditorsK. Eguchi, S. C. Singhal
PublisherElectrochemical Society, Inc.
Pages139-148
Number of pages10
Edition1
ISBN (Electronic)9781607685395
DOIs
Publication statusPublished - 8 Sep 2019
Event16th International Symposium on Solid Oxide Fuel Cells, SOFC XVI - Kyoto, Japan
Duration: 8 Sep 201913 Sep 2019
Conference number: 16
http://www.eguchi-lab.ehcc.kyoto-u.ac.jp/SOFC_XVI/

Publication series

NameECS Transactions
Number1
Volume91
ISSN (Print)1938-6737
ISSN (Electronic)1938-5862

Conference

Conference16th International Symposium on Solid Oxide Fuel Cells, SOFC XVI
Abbreviated titleSOFC
CountryJapan
CityKyoto
Period8/09/1913/09/19
Internet address

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