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Mechanisms of deformation-induced trace element migration in zircon resolved by atom probe and correlative microscopy

Research output: Contribution to journalArticle

Author(s)

Steven M. Reddy, Arie van Riessen, David W. Saxey, Tim E. Johnson, William D. A. Rickard, Denis Fougerouse, Sebastian Fischer, Ty J. Prosa, Katherine P. Rice, David A. Reinhard, Yimeng Chen, David Olson

Abstract

The widespread use of zircon in geochemical and geochronological studies of crustal rocks is underpinned by an understanding of the processes that may modify its composition. Deformation during tectonic and impact related strain is known to modify zircon trace element compositions, but the mechanisms by which this occurs remain unresolved. Here we combine electron backscatter diffraction, transmission Kikuchi diffraction and atom probe microscopy to investigate trace element migration associated with a ∼20 nm wide, 2° low-angle subgrain boundary formed in zircon during a single, high-strain rate, deformation associated with a bolide impact. The low-angle boundary shows elevated concentrations of both substitutional (Y) and interstitial (Al, Mg & Be) ions. The observed compositional variations reflect a dynamic process associated with the recovery of shock-induced vacancies and dislocations into lower energy low-angle boundaries. Y segregation is linked to the migration and localization of oxygen vacancies, whilst the interstitial ions migrate in association with dislocations. These data represent the direct nanoscale observation of geologically-instantaneous, trace element migration associated with crystal plasticity of zircon and provide a framework for further understanding mass transfer processes in zircon.
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Original languageEnglish
Pages (from-to)158-170
Number of pages13
JournalGeochimica et Cosmochimica Acta
Volume195
Early online date22 Sep 2016
DOIs
StatePublished - 15 Dec 2016

    Research areas

  • Atom probe microscopy, Nanoscale, Zircon, Trace element, Geochemistry, Microstructure, EBSD, Reidite, Impact

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