Skip to content

Research at St Andrews

Novel tin oxide spinel-based anodes for Li-ion batteries

Research output: Contribution to journalArticlepeer-review

Author(s)

School/Research organisations

Abstract

In this study, a series of inverse spinel M2SnO4 (M = Mg, Mn, Co) oxides were produced and tested to probe the effect the oxide matrix has on the electrochemical performance of tin oxides. Generally, these new oxides show similar behaviour to SnO2 with the formation of a more complicated mixed metal oxide matrix affecting the potentials of tin reduction and lithium insertion. A reasonable correlation is observed between the potential of the initial reduction of the spinel oxide to metallic tin and the enthalpy of formation of the metal oxide (MO). Amongst the spinels, Mn2SnO4 exhibits the best reversibility and Mg2SnO4 the worst. (C) 2001 Elsevier Science B.V. All rights reserved.

Close

Details

Original languageEnglish
Pages (from-to)223-225
Number of pages3
JournalJournal of Power Sources
Volume97-98
Publication statusPublished - Jul 2001

    Research areas

  • lithium-ion battery, lithium alloy anode, tin oxide, tin oxide spinels, transition metal oxide, LITHIUM

Discover related content
Find related publications, people, projects and more using interactive charts.

View graph of relations

Related by author

  1. Non-stoichiometry, structure and properties of proton-conducting perovskite oxides

    Li, S. & Irvine, J. T. S., Mar 2021, In: Solid State Ionics. 361, 115571.

    Research output: Contribution to journalReview articlepeer-review

  2. Upscaling of co-impregnated La0.20Sr0.25Ca0.45TiO3 anodes for solid oxide fuel cells: a progress report on a decade of academic-industrial collaboration

    Price, R., Cassidy, M., Grolig, J. G., Longo, G. G., Weissen, U. G., Mai, A. G. & Irvine, J. T. S., 12 Feb 2021, In: Advanced Energy Materials. Early View, 21 p., 2003951.

    Research output: Contribution to journalReview articlepeer-review

  3. Microwave irradiation synthesis to obtain La0.7-xPrxCa0.3MnO3 perovskites: electrical and electrochemical performance

    Ferrel-Alvarez, A. C., Domínguez-Crespo, M. A., Cong, H., Torres-Huerta, A. M., Palma-Ramírez, D. & Irvine, J. T. S., 15 Jan 2021, In: Journal of Alloys and Compounds. 851, 156882.

    Research output: Contribution to journalArticlepeer-review

  4. Graphitic-C3N4 coated floating glass beads for photocatalytic destruction of synthetic and natural organic compounds in water under UV light

    Hui, J., Pestana, C. J., Caux, M., Gunaratne, H. Q. N., Edwards, C., Robertson, P. K. J., Lawton, L. A. & Irvine, J. T. S., 15 Jan 2021, In: Journal of Photochemistry and Photobiology A: Chemistry. 405, 112935.

    Research output: Contribution to journalArticlepeer-review

  5. Activation of anion redox in P3 structure cobalt-doped sodium manganese oxide via introduction of transition metal vacancies

    Kim, E. J., Mofredj, K., Pickup, D., Chadwick, A., Irvine, J. T. S. & Armstrong, R., 1 Jan 2021, In: Journal of Power Sources. 481, 229010.

    Research output: Contribution to journalArticlepeer-review

Related by journal

  1. Activation of anion redox in P3 structure cobalt-doped sodium manganese oxide via introduction of transition metal vacancies

    Kim, E. J., Mofredj, K., Pickup, D., Chadwick, A., Irvine, J. T. S. & Armstrong, R., 1 Jan 2021, In: Journal of Power Sources. 481, 229010.

    Research output: Contribution to journalArticlepeer-review

  2. α-PbO2-type niobate as efficient cathode materials for steam and CO2 electrolysis

    Ruan, W., Yue, X., Ni, J., Xie, D. & Ni, C., 31 Jan 2021, In: Journal of Power Sources. 483, 229234.

    Research output: Contribution to journalArticlepeer-review

  3. A novel electrode with multifunction and regeneration for highly efficient and stable symmetrical solid oxide cell

    Tian, Y., Liu, Y., Jia, L., Naden, A., Chen, J., Chi, B., Pu, J., Irvine, J. T. S. & Li, J., 1 Nov 2020, In: Journal of Power Sources. 475, 228620.

    Research output: Contribution to journalArticlepeer-review

  4. Experimental and modeling study of high performance direct carbon solid oxide fuel cell with in situ catalytic steam-carbon gasification reaction

    Xu, H., Chen, B., Zhang, H., Tan, P., Yang, G., Irvine, J. T. S. & Ni, M., 1 Apr 2018, In: Journal of Power Sources. 382, p. 135-143 9 p.

    Research output: Contribution to journalArticlepeer-review

  5. Improved electrochemical performance of LiCoPO4 using eco-friendly aqueous binders

    Kim, E. J., Yue, X., Irvine, J. T. S. & Armstrong, A. R., 1 Nov 2018, In: Journal of Power Sources. 403, p. 11-19 9 p.

    Research output: Contribution to journalArticlepeer-review

ID: 197202

Top