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ORGANOTIN-DMIT COMPLEXES - CRYSTAL-STRUCTURE OF [BU4N][ME2SNCL(DMIT)]

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Author(s)

SMSV DOIDGEHARRISON, RA HOWIE, JTS IRVINE, G SPENCER, JL WARDELL, John Thomas Sirr Irvine

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Abstract

Various organotin-DMIT complexes have been prepared from organotin halides and [Bu4N]2[Ni(DMIT)2] (H2-DMIT = 4,5-dimercapto-1,3-dithiole-2-thione). The crystal structure of [Bu4N][Me2ClSn(DMIT)] (V, R = Me) is reported: the compounds contains a trigonal bipyramidal tin atom in the anion.

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Details

Original languageEnglish
Pages (from-to)C5-C8
Number of pages4
JournalJournal of Organometallic Chemistry
Volume414
Issue number1
Publication statusPublished - 13 Aug 1991

    Research areas

  • METAL, ELECTRONIC-STRUCTURES, SUPERCONDUCTOR, PHASE-TRANSITION, MOLECULAR CONDUCTOR, NI(DMIT)2, X-RAY, RESISTIVITY, <(CH3)4N><NI(DMIT)2>2, 1,3-DITHIOLE-2-THIONE-4,5-DITHIOLATE DMIT

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