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Peri-substituted phosphorus-tellurium systems – an experimental and theoretical investigation of the P∙∙∙Te through-space interaction

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Author(s)

Andreas Nordheider, Emanuel Hupf, Brian Alexander Chalmers, Fergus Ross Knight, Michael Buehl, Stefan Mebs, Liliana Chęcińska, Enno Lork, Paula Sanz Camacho, Sharon Elizabeth Ashbrook, Kasun Sankalpa Athukorala Arachchige, David Bradford Cordes, Alexandra Martha Zoya Slawin, Jens Beckmann, J Derek Woollins

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Abstract

A series of peri-substituted phosphorus-tellurium systems R’Te–Acenap–PR2 (R’ = Ph, p-An, Nap, Mes, Tip; R = iPr, Ph) exhibiting large “through space” spin-spin coupling constants and the “onset” of three-centre four-electron type interactions are presented. The influence of the substituents at the phosphorus and tellurium atoms as well as their behavior upon oxidation (with S, Se) or metal-coordination (Pt, Au) is discussed using NMR spectroscopy, single crystal X-ray diffraction, and advanced DFT studies including NBO, AIM and ELI-D analyses.
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Original languageEnglish
Pages (from-to)2435-2446
JournalInorganic Chemistry
Volume54
Issue number5
Early online date18 Feb 2015
DOIs
Publication statusPublished - 2 Mar 2015

    Research areas

  • Peri-substitution, Phosphorus-tellurium, Through-space spin-spin coupling, Acenaphthene

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