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Perspective: current advances in solid-state NMR spectroscopy

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Perspective : current advances in solid-state NMR spectroscopy. / Ashbrook, Sharon E.; Hodgkinson, Paul.

In: Journal of Chemical Physics, Vol. 149, No. 4, 040901, 28.07.2018.

Research output: Contribution to journalReview articlepeer-review

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Ashbrook, SE & Hodgkinson, P 2018, 'Perspective: current advances in solid-state NMR spectroscopy', Journal of Chemical Physics, vol. 149, no. 4, 040901. https://doi.org/10.1063/1.5038547

APA

Ashbrook, S. E., & Hodgkinson, P. (2018). Perspective: current advances in solid-state NMR spectroscopy. Journal of Chemical Physics, 149(4), [040901]. https://doi.org/10.1063/1.5038547

Vancouver

Ashbrook SE, Hodgkinson P. Perspective: current advances in solid-state NMR spectroscopy. Journal of Chemical Physics. 2018 Jul 28;149(4). 040901. https://doi.org/10.1063/1.5038547

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Ashbrook, Sharon E. ; Hodgkinson, Paul. / Perspective : current advances in solid-state NMR spectroscopy. In: Journal of Chemical Physics. 2018 ; Vol. 149, No. 4.

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@article{d85d4caa4189436f8e7925d2e6adf8e6,
title = "Perspective: current advances in solid-state NMR spectroscopy",
abstract = "In contrast to the rapid and revolutionary impact of solution-state NMR on modern chemistry, the field of solid-state NMR has matured more slowly. This reflects the major technical challenges of much reduced spectral resolution and sensitivity in solid-state as compared to solution-state spectra, as well as the relative complexity of the solid state. In this Perspective, we outline the technique developments that have pushed resolution to intrinsic limits and the approaches, including ongoing major developments in the field of Dynamic Nuclear Polarisation, that have enhanced spectral sensitivity. The information on local structure and dynamics that can be obtained using these gains in sensitivity and resolution is illustrated with a diverse range of examples from large biomolecules, to energy materials and pharmaceuticals, and from both ordered and highly disordered materials. We discuss how parallel developments in quantum chemical calculation, particularly density functional theory, have enabled experimental data to be translated into directly into information on local structure and dynamics, giving rise to the developing field of “NMR crystallography”. ",
author = "Ashbrook, {Sharon E.} and Paul Hodgkinson",
year = "2018",
month = jul,
day = "28",
doi = "10.1063/1.5038547",
language = "English",
volume = "149",
journal = "Journal of Chemical Physics",
issn = "0021-9606",
publisher = "American Institute of Physics",
number = "4",

}

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TY - JOUR

T1 - Perspective

T2 - current advances in solid-state NMR spectroscopy

AU - Ashbrook, Sharon E.

AU - Hodgkinson, Paul

PY - 2018/7/28

Y1 - 2018/7/28

N2 - In contrast to the rapid and revolutionary impact of solution-state NMR on modern chemistry, the field of solid-state NMR has matured more slowly. This reflects the major technical challenges of much reduced spectral resolution and sensitivity in solid-state as compared to solution-state spectra, as well as the relative complexity of the solid state. In this Perspective, we outline the technique developments that have pushed resolution to intrinsic limits and the approaches, including ongoing major developments in the field of Dynamic Nuclear Polarisation, that have enhanced spectral sensitivity. The information on local structure and dynamics that can be obtained using these gains in sensitivity and resolution is illustrated with a diverse range of examples from large biomolecules, to energy materials and pharmaceuticals, and from both ordered and highly disordered materials. We discuss how parallel developments in quantum chemical calculation, particularly density functional theory, have enabled experimental data to be translated into directly into information on local structure and dynamics, giving rise to the developing field of “NMR crystallography”.

AB - In contrast to the rapid and revolutionary impact of solution-state NMR on modern chemistry, the field of solid-state NMR has matured more slowly. This reflects the major technical challenges of much reduced spectral resolution and sensitivity in solid-state as compared to solution-state spectra, as well as the relative complexity of the solid state. In this Perspective, we outline the technique developments that have pushed resolution to intrinsic limits and the approaches, including ongoing major developments in the field of Dynamic Nuclear Polarisation, that have enhanced spectral sensitivity. The information on local structure and dynamics that can be obtained using these gains in sensitivity and resolution is illustrated with a diverse range of examples from large biomolecules, to energy materials and pharmaceuticals, and from both ordered and highly disordered materials. We discuss how parallel developments in quantum chemical calculation, particularly density functional theory, have enabled experimental data to be translated into directly into information on local structure and dynamics, giving rise to the developing field of “NMR crystallography”.

UR - https://aip.scitation.org/journal/jcp

U2 - 10.1063/1.5038547

DO - 10.1063/1.5038547

M3 - Review article

VL - 149

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

SN - 0021-9606

IS - 4

M1 - 040901

ER -

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