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Reactivity of Woollins’ Reagent toward 2-en-1-imines (Schiff bases): a facile approach to synthesize new selenium-phosphorus-nitrogen heterocycles

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DOI

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  • Embargoed (until 4/11/20)

Author(s)

Guoxiong Hua, David B Cordes, Alexandra Slawin, J. Derek Woollins

School/Research organisations

Abstract

Woollins’ Reagent serves as a reductive cycloaddition reagent, reacting with 2‐en‐1‐imines containing a conjugated C=C bond group (Schiff bases) leading to a series of four‐, five‐, six‐membered 1,2‐azaphospholidines incorporating one or two N‐P=Se linkages. Ten single crystal X‐ray structures confirming the formation of these small N‐P‐Se heterocycles are reported.
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Details

Original languageEnglish
Pages (from-to)4682-4689
JournalEuropean Journal of Inorganic Chemistry
Volume2019
Issue number43
Early online date4 Nov 2019
DOIs
Publication statusPublished - 24 Nov 2019

    Research areas

  • Selenium, Woollins’ Reagent, Synthesis, Phosphorus-selenium-nitrogen hetrocycles, X-ray structure

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