Skip to content

Research at St Andrews

Pure silica zeolite-type frameworks: A structural analysis

Research output: Contribution to journalArticlepeer-review

DOI

Author(s)

David S. Wragg, Russell E. Morris, Allen W. Burton

School/Research organisations

Abstract

Since the last major study of silicate crystal structures, many new pure silica zeolite-type frameworks have been discovered. These materials have many interesting properties that are dependent on their structure. We have brought together and analyzed the structures in 35 well-defined frameworks to see how they differ from one another depending on the synthetic route, template, calcination, and composition, and how they differ from the dense silicate phases previously examined. The grand mean values of the Si-O bond distance and the O-Si-O angle are found to be 1.594 angstrom and 109.5 degrees, respectively. The variation and flexibility of the Si-O-Si bond from 133.6 to 180 degrees is discussed, as is the role of fluoride in influencing the O-Si-O bond angles in phases prepared using hydrofluoric acid and ammonium fluoride as mineralizers.

Close

Details

Original languageEnglish
Pages (from-to)1561-1570
Number of pages10
JournalChemistry of Materials
Volume20
DOIs
Publication statusPublished - 26 Feb 2008

    Research areas

  • NEGATIVE THERMAL-EXPANSION, X-RAY-DIFFRACTION, SI-29 MAS NMR, STRUCTURE-DIRECTING AGENT, SOLID-STATE NMR, CRYSTAL-STRUCTURE, POWDER DIFFRACTION, FLUORIDE IONS, ENERGY MINIMIZATION, CLATHRASIL PHASE

Discover related content
Find related publications, people, projects and more using interactive charts.

View graph of relations

Related by author

  1. Solvothermal synthesis of a novel calcium metal-organic 2 framework: high temperature and electrochemical behaviour

    Main, R. M., Cordes, D. B., Desai, A. V., Slawin, A. M. Z., Wheatley, P., Armstrong, A. R. & Morris, R. E., 22 Nov 2021, In: Molecules. 26, 22, 7048.

    Research output: Contribution to journalArticlepeer-review

  2. Rapid microwave-assisted synthesis and electrode optimization of organic anode materials in sodium-ion batteries

    Desai, A. V., Rainer, D. N., Pramanik, A., Cabañero, J. M., Morris, R. E. & Armstrong, A. R., 10 Nov 2021, (E-pub ahead of print) In: Small Methods. Early View, 6 p., 2101016.

    Research output: Contribution to journalArticlepeer-review

  3. Mechanochemical synthesis of sodium carboxylates as anode materials in sodium ion batteries

    Rainer, D. N., Desai, A. V., Armstrong, A. R. & Morris, R. E., 2 Nov 2021, (E-pub ahead of print) In: Journal of Materials Chemistry A. Advance Article, 9 p.

    Research output: Contribution to journalArticlepeer-review

  4. In situ flow pair distribution function analysis to probe the assembly-disassembly-organisation-reassembly (ADOR) mechanism of zeolite IPC-2 synthesis

    Russell, S. E., Henkelis, S. E., Vornholt, S. M., Rainer, D. N., Chapman, K. W. & Morris, R. E., 13 Oct 2021, (E-pub ahead of print) In: Materials Advances. Advance Article, 7 p.

    Research output: Contribution to journalArticlepeer-review

  5. 2021 roadmap for sodium-ion batteries

    Tapia-Ruiz, N., Armstrong, A. R., Alptekin, H., Amores, M. A., Au, H., Barker, J., Boston, R., Brant, W. R., Brittain, J. M., Chen, Y., Chhowalla, M., Choi, Y-S., Costa, S. I. R., Crespo Ribadeneyra, M., Cussen, S. A., Cussen, E. J., David, W. I. F., Desai, A. V., Dickson, S. A. M., Eweka, E. I. & 41 others, Forero-Saboya, J. D., Grey, C. P., Griffin, J. M., Gross, P., Hua, X., Irvine, J. T. S., Johansson, P., Jones, M. O., Karlsmo, M., Kendrick, E., Kim, E., Kolosov, O. V., Li, Z., Mertens, S. F. L., Mogensen, R., Monconduit, L., Morris, R. E., Naylor, A. J., Nikman, S., O’keefe, C. A., Ould, D. M. C., Palgrave, R. G., Poizot, P., Ponrouch, A., Renault, S., Reynolds, E. M., Rudola, A., Sayers, R., Scanlon, D. O., Sen, S., Seymour, V. R., Silván, B., Sougrati, M. T., Stievano, L., Stone, G. S., Thomas, C. I., Titirici, M-M., Tong, J., Wood, T. J., Wright, D. S. & Younesi, R., 26 Jul 2021, In: Journal of Physics: Energy. 3, 3, 89 p., 031503.

    Research output: Contribution to journalArticlepeer-review

Related by journal

  1. Development of the Ca/FeS2 chemistry for thermal batteries

    Dickson, S. A. M., Gover, R. K. B. & Irvine, J. T. S., 9 Sep 2021, (E-pub ahead of print) In: Chemistry of Materials. 33, 18, p. 7367–7378 12 p.

    Research output: Contribution to journalArticlepeer-review

  2. Designed synthesis of STA-30: a small pore zeolite catalyst with topology type SWY

    Chitac, R. G., Bradley, J., McNamara, N., Mayoral, A., Turrina, A. & Wright, P. A., 18 Jun 2021, (E-pub ahead of print) In: Chemistry of Materials. Articles ASAP, 15 p.

    Research output: Contribution to journalArticlepeer-review

  3. Compositional variation in hybrid organic-inorganic lead halide perovskites: kinetically- versus thermodynamically-controlled synthesis

    Tian, J., Zysman-Colman, E. & Morrison, F. D., 13 May 2021, (E-pub ahead of print) In: Chemistry of Materials. Articles ASAP

    Research output: Contribution to journalArticlepeer-review

  4. Cation control of cooperative CO2 adsorption in Li-containing mixed cation forms of the flexible zeolite merlinoite

    Georgieva, V. M., Bruce, E. L., Chitac, R. G., Lozinska, M. M., Hall, A., Murray, C., Smith, R., Turrina, A. & Wright, P. A., 10 Feb 2021, (E-pub ahead of print) In: Chemistry of Materials. Articles ASAP

    Research output: Contribution to journalArticlepeer-review

  5. Local structure and order-disorder transitions in "empty" ferroelectric tetragonal tungsten bronzes

    McNulty, J. A., Pesquera, D., Gardner, J., Rotaru, A., Playford, H. Y., Tucker, M. G., Carpenter, M. A. & Morrison, F. D., 13 Oct 2020, In: Chemistry of Materials. 32, 19, p. 8492-8501

    Research output: Contribution to journalArticlepeer-review

Related by journal

  1. Chemistry of Materials (Journal)

    Finlay Morrison (Reviewer)

    2009 → …

    Activity: Publication peer-review and editorial work typesPeer review of manuscripts

ID: 621476

Top