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Research at St Andrews

Rationalising the effect of reducing agent on the oxazaborolidine-mediated asymmetric reduction of N-substituted imines

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Author(s)

Eirene HM Kirton, Gary Tughan, Russell Edward Morris, Robert A Field

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Abstract

Comparing the effect of borane-based reducing agents on the stereochemical outcome of oxazaborolidine-mediated ketone and N-substituted imine reduction highlights the potential importance of reducing agent structure on the asymmetric sense of imine reduction. (C) 2003 Elsevier Ltd. All rights reserved.

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    Research areas

  • ENANTIOSELECTIVE SYNTHESIS, CHIRAL OXAZABOROLIDINES, BORANE REDUCTION, KETONES, 3,3,3-TRIFLUOROALANINE, CATALYSTS

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