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Redox noninnocent nature of acridine-based Pincer complexes of 3d metals and C–C bond formation

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Author(s)

Prosenjit Daw, Amit Kumar, Dror Oren, Noel A. Espinosa-Jalapa, Dipankar Srimani, Yael Diskin-Posner, Gregory Leitus, Linda Shimon, Raanan Carmieli, Yehoshoa Ben-David, David Milstein

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Abstract

Acridine-based PNP pincer complexes have been previously utilized for several environmentally benign catalytic processes. In light of the recent growth in interest in base-metal catalysis, we report here the synthesis of acridine-PNP pincer complexes of Ni, Co, Fe, and Mn. We also report here the noninnocent redox nature of these complexes that results in the dimerization of pincer complexes by forming a C–C bond at the C9 position of the acridine ring.
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Original languageEnglish
Pages (from-to)279-285
JournalOrganometallics
Volume39
Issue number2
Early online date10 Jan 2020
DOIs
Publication statusPublished - 27 Jan 2020

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