Skip to content

Research at St Andrews

University > Research portal > Research publications > Self-assembly between 1,4-diazabicyclo[2.2.2]octane and bis(...

Self-assembly between 1,4-diazabicyclo[2.2.2]octane and bis(hexafluoroalcohols): solid/liquid phase switching for catalyst recycling

Research output: Contribution to journal › Article › peer-review

DOI

Author(s)

Julien Legros, Daniele Bonnet-Delpon, Benoit Crousse, Alexandra M. Z. Slawin

School/Research organisations

Abstract

Bis(hexafluoroalcohol) derivatives readily self-assemble with 1,4-diazabicyclo[2.2.2]octane through hydrogen bonding. The DABCO (R) catalysts can be released from these crystalline adducts to promote organic transformations. Regeneration of H-bonds allows facile recovery and reuse of this "supramolecular supported catalyst'' (> 10 times).

Close
More...

Details

Original languageEnglish
Pages (from-to)934-936
Number of pages3
JournalCatalysis Science & Technology
Volume2
Issue number5
DOIs
Publication statusPublished - 2012

Discover related content
Find related publications, people, projects and more using interactive charts.

View graph of relations

Related by author

  1. Fast delayed emission in new pyridazine-based compounds

    Krotkus, S., Matulaitis, T., Diesing, S., Copley, G. J., Archer, E., Keum, C., Cordes, D. B., Slawin, A. M. Z., Gather, M. C., Zysman-Colman, E. & Samuel, I. D. W., 7 Jan 2021, In: Frontiers in Chemistry. 8, 572862.

    Research output: Contribution to journal › Article › peer-review

  2. The X-ray Structures of (R)-2,2'-Dimethyl-1,1'-binaphthyl and (±)-2-Bromomethyl-2'-dibromomethyl-1,1'-binaphthyl

    Aitken, R. A., Inwood, R. & Slawin, A. M. Z., 5 Jan 2021, In: Journal of Chemical Crystallography. First Online, 8 p.

    Research output: Contribution to journal › Article › peer-review

  3. (S)-1-(Ethoxycarbonyl)ethyl (2R,5S)-2,5-Dimethyl-1,3-dioxolan-4-one-2-carboxylate

    Aitken, R. A., Haslett, O. E. & Slawin, A. M. Z., 2 Jan 2021, In: Molbank. 2021, 1, 4 p., M1178.

    Research output: Contribution to journal › Article › peer-review

  4. One pot, three dimensionalities: 1D, 2D and 3D zinc coordination polymers with both N- and O- linkers produced in same reaction

    Carpenter-Warren, C. L. & Slawin, A. M. Z., 1 Jan 2021, In: Journal of Solid State Chemistry. 293, 121717.

    Research output: Contribution to journal › Article › peer-review

  5. Isoreticular chemistry of scandium analogues of the multicomponent metal-organic framework MIL-142

    Prasad, R. R. R., Pleass, C., Rigg, A., Cordes, D. B., Lozinska, M. M., Georgieva, V. M., Hoffmann, F., Slawin, A. M. Z. & Wright, P. A., 8 Dec 2020, In: CrystEngComm. 11 p.

    Research output: Contribution to journal › Article › peer-review

Related by journal

  1. Ligand electronic fine-tuning and its repercussion on the photocatalytic activity and mechanistic pathways of the copper-photocatalysed aza-Henry Reaction

    Li, C., Dickson, R., Rockstroh, N., Rabeah, J., Cordes, D. B., Slawin, A. M. Z., Hünemörder, P., Spannenberg, A., Buehl, M., Mejía, E., Zysman-Colman, E. & Kamer, P. C. J., 18 Sep 2020, In: Catalysis Science & Technology. Advance Article, 12 p.

    Research output: Contribution to journal › Article › peer-review

  2. Effect of oxygen coordination environment of Ca-Mn oxides on catalytic performance of Pd supported catalysts for aerobic oxidation of 5-hydroxymethyl-2-furfural

    Yang, J., Yu, H., Wang, Y., Qi, F., Liu, H., Lou, L-L., Yu, K., Zhou, W. & Liu, S., 7 Dec 2019, In: Catalysis Science & Technology. 9, 23, p. 6659-6668

    Research output: Contribution to journal › Article › peer-review

  3. Photoredox catalysts based on Earth-abundant metal complexes

    Hockin, B., Li, C., Robertson, N. & Zysman-Colman, E., 21 Feb 2019, In: Catalysis Science & Technology. 9, 4, p. 889-915

    Research output: Contribution to journal › Article › peer-review

  4. Towards practical earth abundant reduction catalysis: design of improved catalysts for manganese catalysed hydrogenation

    Widegren, M. B. & Clarke, M. L., 7 Nov 2019, In: Catalysis Science & Technology. 9, 21, p. 6047-6058

    Research output: Contribution to journal › Article › peer-review

  5. Less hindered ligands give improved catalysts for the nickel catalysed Grignard cross-coupling of aromatic ethers

    Harkness, G. J. & Clarke, M. L., 7 Jan 2018, In: Catalysis Science & Technology. 8, 1, p. 328-334

    Research output: Contribution to journal › Article › peer-review

ID: 28461068

Top