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Six-coordinated Cd(II) centres as four- or six-connected nodes in coordination polymer networks containing bis(4-pyridyl)amine

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Author(s)

David B. Cordes, Lyall R. Hanton, Mark D. Spicer

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Abstract

The networks for 2 and 3 were 4-fold interpenetrated and isotopological. The reaction of CdSO4 with bpaH+ led to the formation of a two-dimensional (2D) hydrogen-bonded net (4). Complex 4 consisted of discrete six-coordinate mononuclear units linked into a 2D network by a number of different hydrogen-bonding interactions. The topological analysis of this network showed it to be reminiscent of a 2D diagonal section of an α-polonium network.

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Original languageEnglish
Pages (from-to)328-336
Number of pages9
JournalCrystal Growth & Design
Volume7
Issue number2
Early online date16 Dec 2006
DOIs
Publication statusPublished - Feb 2007

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