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Solvothermal indium fluoride chemistry: Syntheses and crystal structures of K5In3F14, beta-(NH4)(3)InF6 and [NH4](3)[C6H21N4](2)[In4F21]

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Abstract

The solvothermal syntheses and crystal structures of three indium fluorides are presented. K5In3F14 (1) and beta-(NH4)(3)InF6 (2) are variants on known inorganic structure types chiolite and cryolite, respectively, with the latter exhibiting a complex and apparently novel structural distortion. [NH4](3)[C6H21N4](2) [In4F21] (3) represents a new hybrid composition displaying a unique trimeric metal fluoride building unit. (C) 2009 Elsevier Inc. All rights reserved.

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Original languageEnglish
Pages (from-to)356-360
Number of pages5
JournalJournal of Solid State Chemistry
Volume183
Issue number2
DOIs
StatePublished - Feb 2010

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