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Structural changes of synthetic paulingite (Na,H-ECR-18) upon dehydration and CO2 adsorption

Research output: Contribution to journalArticle

Author(s)

A.G. Greenaway, J. Shin, P.A. Cox, E. Shiko, S.P. Thompson, S. Brandani, S.B. Hong, P.A. Wright

School/Research organisations

Abstract

The structure of dehydrated calcined ECR-18, synthetic paulingite, topology type PAU, unit cell composition Na132H28Si512Al160O1344, has been determined by Rietveld refinement against synchrotron X-ray powder diffraction data. Upon dehydration the symmetry of Na,H-ECR-18 changes from Im3m to I 43m, with a corresponding decrease of cubic unit cell a parameter from 34.89412(1) A to 33.3488(3) A. This occurs as the framework distorts to afford closer coordination of Na+ cations by framework O atoms in 8-ring window sites of the seven cage types present. Na+ cations in 8R sites block the access of N2 molecules to the internal pore space at 77 K but CO2 adsorption at 308 K is observed, and is postulated to occur via a 'trapdoor' mechanism. In situ PXRD during CO2 adsorption at pressures up to 10 bar show reversible broadening of diffraction peaks that is attributed to local crystallographic strain.

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Details

Original languageEnglish
Pages (from-to)223-231
Number of pages9
JournalZeitschrift fur Kristallographie
Volume230
Issue number4
Early online date18 Mar 2015
DOIs
Publication statusPublished - Apr 2015

    Research areas

  • Carbon dioxide adsoption, Cation locations, Dehydrated structure, Synthetic paulingite, Trapdoor zeolite

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