Skip to content

Research at St Andrews

Structural diversity in hybrid lead halides templated by 4-methylimidazolium

Research output: Contribution to journalArticlepeer-review

Open Access Status

  • Embargoed (until 2/08/22)

Author(s)

School/Research organisations

Abstract

We present several new hybrid organic-inorganic lead(II) bromide materials with interesting polyhedral connectivity templated by [4-MeImH] ([4-MeImH] = 4-methylimidazolium). These include two new examples of a 1D structure-type consisting of edge-sharing chains ([4-MeImH]PbBr3 and [4-MeImH]0.6[ImH]0.4PbBr3, [ImH] = imidazolium); the first example of a 2D layered material containing 7-coordinate Pb, and featuring edge- and face-sharing polyhedra ([4-MeImH]Pb2Br5) and two examples of materials consisting of corner- and face-sharing octahedra; [ImH]PbBr3, which has a 4H-perovskite structure and [4-MeImH]4[ImH]5Pb6Br21, which has a structural resemblance to the 4H-perovskite, but incorporates terminal Br ligands leading to a complex layered structure.
Close

Details

Original languageEnglish
Article number122466
JournalJournal of Solid State Chemistry
VolumeIn press
Early online date2 Aug 2021
DOIs
Publication statusE-pub ahead of print - 2 Aug 2021

    Research areas

  • Single crystal X-ray diffraction, Lead halides, Polyhderal connectivity, Strucutre-directing effects, Hybrid organic-inorganic

Discover related content
Find related publications, people, projects and more using interactive charts.

View graph of relations

Related by author

  1. New variants of (110)-oriented layered lead bromide perovskites, templated by formamidinium or pyrazolium

    Guo, Y., Elliott, C., McNulty, J., Cordes, D., Slawin, A. & Lightfoot, P., 12 Aug 2021, (E-pub ahead of print) In: European Journal of Inorganic Chemistry. Early View

    Research output: Contribution to journalArticlepeer-review

  2. Structural variations in (001)-oriented layered lead halide perovskites templated by 1,2,4-triazolium

    Guo, Y-Y., Yang, L-J., McNulty, J. A., Slawin, A. M. Z. & Lightfoot, P., 10 Nov 2020, (E-pub ahead of print) In: Dalton Transactions. In press

    Research output: Contribution to journalArticlepeer-review

  3. Variable dimensionality in 'hollow' hybrid tin iodide perovskites

    McNulty, J. A., Slawin, A. M. Z. & Lightfoot, P., 26 Oct 2020, (E-pub ahead of print) In: Dalton Transactions. Advance Articles

    Research output: Contribution to journalArticlepeer-review

  4. Structural variations in manganese halide chain compounds mediated by methylimidazolium isomers

    Han, C., Cordes, D. B., Slawin, A. M. Z. & Lightfoot, P., 13 Oct 2020, In: Crystals. 10, 10, 10 p., 930.

    Research output: Contribution to journalArticlepeer-review

  5. Structure-directing effects in (110)-layered hybrid perovskites containing two distinct organic moieties

    Guo, Y-Y., McNulty, J. A., Mica, N., Samuel, I. D. W., Slawin, A. M. Z., Buehl, M. & Lightfoot, P., 28 Aug 2019, In: Chemical Communications. 55, 67, p. 9935-9938

    Research output: Contribution to journalArticlepeer-review

Related by journal

  1. Journal of Solid State Chemistry (Journal)

    Finlay Morrison (Reviewer)

    2010 → …

    Activity: Publication peer-review and editorial work typesPeer review of manuscripts

Related by journal

  1. Maximising carbonate content in sodium-carbonate Co-substituted hydroxyapatites prepared by aqueous precipitation reaction

    Nowicki, D. A., Skakle, J. M. S. & Gibson, I. R., May 2021, In: Journal of Solid State Chemistry. 297, 122042.

    Research output: Contribution to journalArticlepeer-review

  2. One pot, three dimensionalities: 1D, 2D and 3D zinc coordination polymers with both N- and O- linkers produced in same reaction

    Carpenter-Warren, C. L. & Slawin, A. M. Z., 1 Jan 2021, In: Journal of Solid State Chemistry. 293, 121717.

    Research output: Contribution to journalArticlepeer-review

  3. Phase transitions in the hexagonal tungsten bronze RbNbW2O9

    McNulty, J. A., Gibbs, A. S., Lightfoot, P. & Morrison, F. D., Jun 2020, In: Journal of Solid State Chemistry. 286, 121275.

    Research output: Contribution to journalArticlepeer-review

ID: 275200972

Top