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Structure-directing effects in (110)-layered hybrid perovskites containing two distinct organic moieties

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Abstract

The hybrid perovskites (ImH)(GuH)PbBr4 and (TzH)(GuH)PbBr4 (ImH+ = imidazolium, GuH+ = guanidinium, TzH+ = 1,2,4-triazolium) both adopt (110)-oriented layer structures. However, the GuH+ cation adopts differing crystallographic sites in the two structures (intra-layer versus inter-layer); this is discussed in terms of the sizes of the organic cations and their hydrogen-bonding preferences.
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Original languageEnglish
JournalChemical Communications
VolumeAdvance Article
Early online date25 Jul 2019
DOIs
Publication statusE-pub ahead of print - 25 Jul 2019

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