Skip to content

Research at St Andrews

Structure/property correlations in the new ferroelectric Bi5PbTi3O14Cl and related layered oxyhalide intergrowth phases

Research output: Contribution to journalArticlepeer-review

DOI

Author(s)

School/Research organisations

Abstract

The crystal structure and electrophysical properties of the layered intergrowth phase Bi5PbTi3O14Cl have been studied using powder neutron diffraction, ac impedance and second harmonic generation methods. This phase adopts a structure based on a regular intergrowth of Aurivillius-like and Sillen-like blocks in the layer sequence ...[M2O2][M2Ti3O10][M2O2][ Cl]..., and is therefore closely structurally related to the well-known ferroelectric Bi4Ti3O12. The phase adopts the polar orthorhombic space group P2an at temperatures below 590 degreesC, and transforms directly to a centrosymmetric tetragonal phase, space group P4/mmm, at that temperature. This abrupt structural phase transition is consistent with a sudden loss of SHG signal and a dielectric maximum at the same temperature. The structural features and electrophysical behaviour of this phase in relation to Bi4Ti3O12 and related layered oxides/oxyhalides are discussed.

Close

Details

Original languageEnglish
Pages (from-to)3413-3418
Number of pages6
JournalJournal of Materials Chemistry
Volume12
DOIs
Publication statusPublished - 2002

    Research areas

  • STRUCTURE REFINEMENT, BI4TI3O12, BI4NBO8CL

Discover related content
Find related publications, people, projects and more using interactive charts.

View graph of relations

Related by author

  1. Non-stoichiometry, structure and properties of proton-conducting perovskite oxides

    Li, S. & Irvine, J. T. S., Mar 2021, In: Solid State Ionics. 361, 115571.

    Research output: Contribution to journalReview articlepeer-review

  2. Upscaling of co-impregnated La0.20Sr0.25Ca0.45TiO3 anodes for solid oxide fuel cells: a progress report on a decade of academic-industrial collaboration

    Price, R., Cassidy, M., Grolig, J. G., Longo, G. G., Weissen, U. G., Mai, A. G. & Irvine, J. T. S., 12 Feb 2021, In: Advanced Energy Materials. Early View, 21 p., 2003951.

    Research output: Contribution to journalReview articlepeer-review

  3. Microwave irradiation synthesis to obtain La0.7-xPrxCa0.3MnO3 perovskites: electrical and electrochemical performance

    Ferrel-Alvarez, A. C., Domínguez-Crespo, M. A., Cong, H., Torres-Huerta, A. M., Palma-Ramírez, D. & Irvine, J. T. S., 15 Jan 2021, In: Journal of Alloys and Compounds. 851, 156882.

    Research output: Contribution to journalArticlepeer-review

  4. Graphitic-C3N4 coated floating glass beads for photocatalytic destruction of synthetic and natural organic compounds in water under UV light

    Hui, J., Pestana, C. J., Caux, M., Gunaratne, H. Q. N., Edwards, C., Robertson, P. K. J., Lawton, L. A. & Irvine, J. T. S., 15 Jan 2021, In: Journal of Photochemistry and Photobiology A: Chemistry. 405, 112935.

    Research output: Contribution to journalArticlepeer-review

  5. Activation of anion redox in P3 structure cobalt-doped sodium manganese oxide via introduction of transition metal vacancies

    Kim, E. J., Mofredj, K., Pickup, D., Chadwick, A., Irvine, J. T. S. & Armstrong, R., 1 Jan 2021, In: Journal of Power Sources. 481, 229010.

    Research output: Contribution to journalArticlepeer-review

Related by journal

  1. Long-range exciton diffusion in non-fullerene acceptors and coarse bulk heterojunctions enable highly efficient organic photovoltaics

    Sajjad, M. T., Ruseckas, A., Jagadamma, L. K., Zhang, Y. & Samuel, I. D. W., 21 Jul 2020, In: Journal of Materials Chemistry. 8, 31, p. 15687-15694 8 p.

    Research output: Contribution to journalArticlepeer-review

  2. Hexagonal perovskite related oxide ion conductor Ba3NbMoO8.5: phase transition, temperature evolution of the local structure and properties

    Chambers, M. S., McCombie, K. S., Auckett, J. E., McLaughlin, A. C., Irvine, J. T. S., Chater, P. A., Evans, J. S. O. & Evans, I. R., 28 Nov 2019, In: Journal of Materials Chemistry. 7, 44, p. 25503-25510 8 p.

    Research output: Contribution to journalArticlepeer-review

  3. Magneto-structural correlations of novel kagomé-type metal organic frameworks

    H. Mohideen, M. I., Lei, C., Tuček, J., Malina, O., Brivio, F., Kasneryk, V., Huang, Z., Mazur, M., Zou, X., Nachtigall, P., Čejka, J. & Morris, R. E., 14 Jun 2019, In: Journal of Materials Chemistry. 7, 22, p. 6692-6697 6 p.

    Research output: Contribution to journalArticlepeer-review

  4. Revealing resonance effects and intramolecular dipole interactions in the positional isomers of benzonitrile-core thermally activated delayed fluorescence materials

    Kukhta, N. A., Higginbotham, H. F., Matulaitis, T., Danos, A., Bismillah, A. N., Haase, N., Etherington, M. K., Yufit, D. S., McGonigal, P. R., Gražulevičius, J. V. & Monkman, A. P., 14 Aug 2019, In: Journal of Materials Chemistry. 7, 30, p. 9184-9194 11 p.

    Research output: Contribution to journalArticlepeer-review

  5. STA-27, a porous Lewis acidic scandium MOF with an unexpected topology type prepared with 2,3,5,6-tetrakis(4-carboxyphenyl)pyrazine

    Prasad, R., Seidner, S., Cordes, D. B., Lozinska, M., Dawson, D., Thompson, M., Düren, T., Chakarova, K., Mihaylov, M., Hadjiivanov, K., Hoffmann, F., Slawin, A. M. Z., Ashbrook, S. E., Clarke, M. & Wright, P., 14 Mar 2019, In: Journal of Materials Chemistry. 7, 10, p. 5685-5701

    Research output: Contribution to journalArticlepeer-review

Related by journal

  1. Journal of Materials Chemistry (Journal)

    Finlay Morrison (Reviewer)

    2008 → …

    Activity: Publication peer-review and editorial work typesPeer review of manuscripts

  2. Journal of Materials Chemistry (Journal)

    John Thomas Sirr Irvine (Member of editorial board)

    2007 → …

    Activity: Publication peer-review and editorial work typesEditor of research journal

ID: 198393

Top